Effect of nicotinamide on electrodeposition of Al from aluminium chloride (AlCl3)-1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquids
文献类型:期刊论文
作者 | Zhang, Qinqin1,2; Wang, Qian1; Zhang, Suojiang1; Lu, Xingmei1 |
刊名 | JOURNAL OF SOLID STATE ELECTROCHEMISTRY
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出版日期 | 2014 |
卷号 | 18期号:1页码:257-267 |
关键词 | Ionic liquid Aluminium Electrodeposition Nicotinamide Additive |
ISSN号 | 1432-8488 |
通讯作者 | Zhang, SJ (reprint author), Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China. |
英文摘要 | The effect of nicotinamide on the electrodeposition of Al was first investigated in the ionic liquid [Bmim]Cl/AlCl3 (40.0/60.0, mol%) by means of cyclic voltammetry and chronopotentiometry. Cyclic voltammograms indicated that nicotinamide produced an inhibiting effect on Al deposition, which can be attributed to the adsorption of nicotinamide on the electrode surface. Galvanostatic deposition experiments revealed that nicotinamide served as a very effective leveling agent, resulting in highly uniform and smooth Al deposits. The effects of temperature and current density on the surface morphologies and crystal orientations of Al deposits were also studied. As the temperature was increased from 30 to 70 A degrees C, the grain size of Al deposits increased but the intensity of the preferred (200) crystallographic plane weakened. By contrast, the opposite applied just with increasing current density from 3.4 to 9.4 mA cm(-2). |
WOS标题词 | Science & Technology ; Physical Sciences |
学科主题 | Electrochemistry |
类目[WOS] | Electrochemistry |
研究领域[WOS] | Electrochemistry |
关键词[WOS] | TEMPERATURE MOLTEN-SALTS ; NANOCRYSTALLINE ALUMINUM ; SURFACE-MORPHOLOGY ; MAGNESIUM ALLOY ; STAINLESS-STEEL ; CORROSION ; COATINGS ; ELECTROCRYSTALLIZATION ; DEPOSITION ; ADDITIVES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000329105400030 |
源URL | [http://ir.ipe.ac.cn/handle/122111/15256] ![]() |
专题 | 过程工程研究所_研究所(批量导入) |
作者单位 | 1.Chinese Acad Sci, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Qinqin,Wang, Qian,Zhang, Suojiang,et al. Effect of nicotinamide on electrodeposition of Al from aluminium chloride (AlCl3)-1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquids[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2014,18(1):257-267. |
APA | Zhang, Qinqin,Wang, Qian,Zhang, Suojiang,&Lu, Xingmei.(2014).Effect of nicotinamide on electrodeposition of Al from aluminium chloride (AlCl3)-1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquids.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,18(1),257-267. |
MLA | Zhang, Qinqin,et al."Effect of nicotinamide on electrodeposition of Al from aluminium chloride (AlCl3)-1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquids".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 18.1(2014):257-267. |
入库方式: OAI收割
来源:过程工程研究所
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