Effects of Solvent Evaporation Rate and Poly(acrylic acid) on Formation of Poly(ethylene oxide)-block-polystyrene Micelles from Emulsion
文献类型：期刊论文
| 作者 | Su, Mei ; Su, Zhaohui |
| 刊名 | macromolecules
 |
| 出版日期 | 2014 |
| 卷号 | 47期号:4页码:1428-1432 |
| 关键词 | BLOCK-COPOLYMER MICELLES POLYSTYRENE-BLOCK-POLY(ETHYLENE OXIDE) MICELLES MULTIPLE MORPHOLOGIES DRUG-DELIVERY INTERFACIAL INSTABILITIES BIOLOGICAL SIGNIFICANCE DIBLOCK COPOLYMERS COMPLEXATION WATER FLUORESCENCE |
| 通讯作者 | su,zh |
| 英文摘要 | in this work, a solution of poly(ethylene oxide)-block-polystyrene (peo-b-ps) block copolymer in an organic solvent was dispersed in water to form an emulsion in the presence of poly(acrylic acid) (paa), which upon solvent evaporation produced micelles, and the "emulsion and solvent evaporation" process was studied. it was found that paa interacted with the peo corona of the micelles to reduce the curvature, transforming the aggregates from cylinders into vesicles when 1,2-dichloroethane was the solvent. however, when a more volatile solvent, dichloromethane, was used instead, cylindrical micelles were obtained. even from 1,2-dichloroethane, cylinders were the predominant species when the initial solution concentration was higher (i.e., shorter evaporation process) or when paa with a much higher molecular weight was used. on the basis of these observations, the interplay between the solvent evaporation rate and the mass transport and chain reorganization at the inteface is discussed. in addition, some intermediate structures were observed, which provided insight into the assembly process. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000332059300022 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/52085]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Su, Mei,Su, Zhaohui. Effects of Solvent Evaporation Rate and Poly(acrylic acid) on Formation of Poly(ethylene oxide)-block-polystyrene Micelles from Emulsion[J]. macromolecules,2014,47(4):1428-1432. |
| APA | Su, Mei,&Su, Zhaohui.(2014).Effects of Solvent Evaporation Rate and Poly(acrylic acid) on Formation of Poly(ethylene oxide)-block-polystyrene Micelles from Emulsion.macromolecules,47(4),1428-1432. |
| MLA | Su, Mei,et al."Effects of Solvent Evaporation Rate and Poly(acrylic acid) on Formation of Poly(ethylene oxide)-block-polystyrene Micelles from Emulsion".macromolecules 47.4(2014):1428-1432. |
入库方式： OAI收割
来源：长春应用化学研究所
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