Evaluation of Hydrophobic Polyvinyl-Alcohol Formaldehyde Sponges As Absorbents for Oil Spill
文献类型：期刊论文
| 作者 | Pan, Yanxiong ; Shi, Kai ; Peng, Chao ; Wang,Weicai ; Liu,Zhi ; Ji,Xiangling |
| 刊名 | acs applied materials & interfaces
 |
| 出版日期 | 2014 |
| 卷号 | 6期号:11页码:8651-8659 |
| 关键词 | SORPTION PROPERTIES HIGHLY EFFICIENT ORGANIC-SOLVENTS CARBON NANOTUBE COTTON FIBERS REMOVAL WATER ABSORPTION SORBENT CLEANUP |
| 通讯作者 | ji,xl |
| 英文摘要 | macroporous materials are a class of absorbents used for oil spill cleanup. in this article, novel macroporous and hydrophobic polyvinyl formaldehyde (pvf-h) sponges were prepared by the reaction of stearoyl chloride with hydroxyl groups of hydrophilic pvf sponge at different temperatures. attenuated total reflectance-infrared (atr-ir) spectroscopy confirmed the successfully anchoring of hydrophobic stearoyl groups on the pvf networks. scanning electron microscopy (sem) images demonstrated that the as prepared pvf-h had interconnected open cell structures, and mercury intrusion porosimetry indicated that the average pore size ranged from 60 to 90 mu m and porosity was greater than 94.8%. such pvf-h sponges can absorb oil products effectively, such as toluene, n-hexane, kerosene, soybean oil, hydraulic oil, and crude oil up to 13.7 g.g(-1) to 56.6 g.g(-1) and this level of absorption was approximately 2-4 times higher than that absorbed by commercial polypropylene nonwoven mat. in low-viscosity oils, the samples can reach the saturated absorption amount only in 1 min, but in higher-viscosity oils, absorption equilibrium can be reached in 10 min. in a simulated oil slick system, these macroporous and hydrophobic sponges can still maintain high oil absorption capacities within the range of 14.4 g.g(-1) to 57.6 g.g(-1), whereas a relatively low absorption rate (approximately 20 min) indicated high absorption performance and excellent selectivity in the oil-water mixture. in addition, the absorbed oils were collected effectively only through a simple squeeze. the pvf-h sponges were subjected to 35 absorption-squeeze cycles and exhibited good reusability and 90% recovery for oils. the samples prepared at different temperatures differed in their absorption capacities to some extent. however, this new kind of macroporous and pvf-h sponges had excellent absorption performance on oil products. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000337336900084 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/52364]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Pan, Yanxiong,Shi, Kai,Peng, Chao,et al. Evaluation of Hydrophobic Polyvinyl-Alcohol Formaldehyde Sponges As Absorbents for Oil Spill[J]. acs applied materials & interfaces,2014,6(11):8651-8659. |
| APA | Pan, Yanxiong,Shi, Kai,Peng, Chao,Wang,Weicai,Liu,Zhi,&Ji,Xiangling.(2014).Evaluation of Hydrophobic Polyvinyl-Alcohol Formaldehyde Sponges As Absorbents for Oil Spill.acs applied materials & interfaces,6(11),8651-8659. |
| MLA | Pan, Yanxiong,et al."Evaluation of Hydrophobic Polyvinyl-Alcohol Formaldehyde Sponges As Absorbents for Oil Spill".acs applied materials & interfaces 6.11(2014):8651-8659. |
入库方式： OAI收割
来源：长春应用化学研究所
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