Pd-II-Catalyzed Mild C-H ortho Arylation and Intramolecular Animation Oriented by a Phosphinamide Group
文献类型:期刊论文
作者 | Guan, Jing ; Wu, Guo-Jie ; Han, Fu-She |
刊名 | chemistry-a european journal
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出版日期 | 2014 |
卷号 | 20期号:12页码:3301-3305 |
关键词 | CROSS-COUPLING REACTIONS ARYL HYDROGEN PHOSPHATES BOND FORMATION DIALKYL PHOSPHITES ROOM-TEMPERATURE DIRECTING GROUP BORONIC ACIDS PALLADIUM COPPER ACTIVATION |
通讯作者 | han,fs |
英文摘要 | a novel protocol for the pd-catalyzed ortho-arylation of aryl phosphinamide with boronic acid is reported. by using phosphinamide as a new directing group, the reaction proceeds efficiently under mild conditions at 40 degrees c. mechanistic studies reveal that the reaction proceeds via a pd-ii to pd-0 cycle. the phosphinamide group is also shown to be an effective orienting group for direct ch amination. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000332747400009 |
源URL | [http://ir.ciac.jl.cn/handle/322003/52401] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Guan, Jing,Wu, Guo-Jie,Han, Fu-She. Pd-II-Catalyzed Mild C-H ortho Arylation and Intramolecular Animation Oriented by a Phosphinamide Group[J]. chemistry-a european journal,2014,20(12):3301-3305. |
APA | Guan, Jing,Wu, Guo-Jie,&Han, Fu-She.(2014).Pd-II-Catalyzed Mild C-H ortho Arylation and Intramolecular Animation Oriented by a Phosphinamide Group.chemistry-a european journal,20(12),3301-3305. |
MLA | Guan, Jing,et al."Pd-II-Catalyzed Mild C-H ortho Arylation and Intramolecular Animation Oriented by a Phosphinamide Group".chemistry-a european journal 20.12(2014):3301-3305. |
入库方式: OAI收割
来源:长春应用化学研究所
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