Electrochemiluminescence Detection of TNT by Resonance Energy Transfer through the Formation of a TNT-Amine Complex
文献类型：期刊论文
| 作者 | Qi, Wenjing ; Xu, Min ; Pang, Lei ; Liu,Zhongyuan ; Zhang,Wei ; Majeed,Saadat ; Xu,Guobao |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2014 |
| 卷号 | 20期号:16页码:4829-4835 |
| 关键词 | SILICA NANOPARTICLES ELECTROGENERATED CHEMILUMINESCENCE ULTRASENSITIVE DETECTION FLUORESCENCE DETECTION GOLD NANOPARTICLES QUANTUM DOTS EXPLOSIVES 2 STRATEGY SURFACE 4 6-TRINITROTOLUENE |
| 通讯作者 | xu,gb |
| 英文摘要 | 2,4,6-trinitrotoluene (tnt) is a widely used nitroaromatic explosive with significant detrimental effects on the environment and human health. its detection is of great importance. in this study, both electrochemiluminescence (ecl)-based detection of tnt through the formation of a tnt-amine complex and the detection of tnt through electrochemiluminescence resonance energy transfer (ecret) are developed for the first time. 3-aminopropyltriethoxysilane (aptes)-modified [ru(phen)(3)](2+) (phen=1,10-phenanthroline)-doped silica nanoparticles (rusinps) with uniform sizes of (73 +/- 3)nm were synthesized. tnt can interact with aptes-modified rusinps through charge transfer from electron-rich amines in the rusinps to the electron-deficient aromatic ring of tnt to form a red tnt-amine complex. the absorption spectrum of this complex overlaps with the ecl spectrum of the aptes-modified rusinps/triethylamine system. as a result, ecl signals of the aptes-modified rusinps/triethylamine system are turned off in the presence of tnt owing to resonance energy transfer from electrochemically excited rusinps to the tnt-amine complex. this ecret method has been successfully applied for the sensitive determination of tnt with a linear range from 1x10(-9) to 1x10(-6)m with a fast response time within 1min. the limit of detection is 0.3nm. the method exhibits good selectivity towards 2,4-dinitrotoluene, p-nitrotoluene, nitrobenzene, phenol, p-quinone, 8-hydroxyquinoline, p-phenylenediamine, k-3[fe(cn)(6)], fe3+, no3-, no2-, cr3+, fe2+, pb2+, so32-, formaldehyde, oxalate, proline, and glycine. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000334080800039 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/52404]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qi, Wenjing,Xu, Min,Pang, Lei,et al. Electrochemiluminescence Detection of TNT by Resonance Energy Transfer through the Formation of a TNT-Amine Complex[J]. chemistry-a european journal,2014,20(16):4829-4835. |
| APA | Qi, Wenjing.,Xu, Min.,Pang, Lei.,Liu,Zhongyuan.,Zhang,Wei.,...&Xu,Guobao.(2014).Electrochemiluminescence Detection of TNT by Resonance Energy Transfer through the Formation of a TNT-Amine Complex.chemistry-a european journal,20(16),4829-4835. |
| MLA | Qi, Wenjing,et al."Electrochemiluminescence Detection of TNT by Resonance Energy Transfer through the Formation of a TNT-Amine Complex".chemistry-a european journal 20.16(2014):4829-4835. |
入库方式： OAI收割
来源：长春应用化学研究所
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