Reversible transient nucleation in ionic solutions as the precursor of ion crystallization
文献类型:期刊论文
作者 | Wang, YT![]() |
刊名 | EPL
![]() |
出版日期 | 2014 |
卷号 | 107期号:3页码:30005 |
关键词 | HOMOGENEOUS NUCLEATION ELECTROLYTE-SOLUTIONS ACTIVITY-COEFFICIENTS AQUEOUS-SOLUTIONS DYNAMICS PHASE SIMULATION AGGREGATION CRITICALITY CRYSTALS |
ISSN号 | 0295-5075 |
通讯作者 | Ren, G (reprint author), Chinese Acad Sci, Inst Theoret Phys, State Key Lab Theoret Phys, 55 East Zhongguancun Rd,POB 2735, Beijing 100190, Peoples R China. |
英文摘要 | Molecular dynamics simulations for aqueous sodium chloride solutions were carried out at various concentrations. Supplementary to the Debye-Huckel theory, reversible transient nucleation of ions was observed even in dilute solutions. The average size of formed ion clusters and the lifetime of ion pairs increases with concentration until the saturation point, when ion clusters become stable and individual ions adjust their positions to form ordered lattice structures, leading to irreversible ion crystallization, which is beyond the description of the classical nucleation theory. Copyright (C) EPLA, 2014 |
学科主题 | Physics |
收录类别 | SCI |
资助信息 | National Basic Research Program of China (973 program) [2013CB932804]; National Natural Science Foundation of China [91227115, 11121403]; Hundred Talent Program of the Chinese Academy of Sciences (CAS) |
原文出处 | http://dx.doi.org/10.1209/0295-5075/107/30005 |
语种 | 英语 |
WOS记录号 | WOS:000340780100005 |
公开日期 | 2015-06-03 |
源URL | [http://ir.itp.ac.cn/handle/311006/15692] ![]() |
专题 | 理论物理研究所_理论物理所1978-2010年知识产出 |
推荐引用方式 GB/T 7714 | Wang, YT. Reversible transient nucleation in ionic solutions as the precursor of ion crystallization[J]. EPL,2014,107(3):30005. |
APA | Wang, YT.(2014).Reversible transient nucleation in ionic solutions as the precursor of ion crystallization.EPL,107(3),30005. |
MLA | Wang, YT."Reversible transient nucleation in ionic solutions as the precursor of ion crystallization".EPL 107.3(2014):30005. |
入库方式: OAI收割
来源:理论物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。