中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Reversible transient nucleation in ionic solutions as the precursor of ion crystallization

文献类型:期刊论文

作者Wang, YT
刊名EPL
出版日期2014
卷号107期号:3页码:30005
关键词HOMOGENEOUS NUCLEATION ELECTROLYTE-SOLUTIONS ACTIVITY-COEFFICIENTS AQUEOUS-SOLUTIONS DYNAMICS PHASE SIMULATION AGGREGATION CRITICALITY CRYSTALS
ISSN号0295-5075
通讯作者Ren, G (reprint author), Chinese Acad Sci, Inst Theoret Phys, State Key Lab Theoret Phys, 55 East Zhongguancun Rd,POB 2735, Beijing 100190, Peoples R China.
英文摘要Molecular dynamics simulations for aqueous sodium chloride solutions were carried out at various concentrations. Supplementary to the Debye-Huckel theory, reversible transient nucleation of ions was observed even in dilute solutions. The average size of formed ion clusters and the lifetime of ion pairs increases with concentration until the saturation point, when ion clusters become stable and individual ions adjust their positions to form ordered lattice structures, leading to irreversible ion crystallization, which is beyond the description of the classical nucleation theory. Copyright (C) EPLA, 2014
学科主题Physics
收录类别SCI
资助信息National Basic Research Program of China (973 program) [2013CB932804]; National Natural Science Foundation of China [91227115, 11121403]; Hundred Talent Program of the Chinese Academy of Sciences (CAS)
原文出处http://dx.doi.org/10.1209/0295-5075/107/30005
语种英语
WOS记录号WOS:000340780100005
公开日期2015-06-03
源URL[http://ir.itp.ac.cn/handle/311006/15692]  
专题理论物理研究所_理论物理所1978-2010年知识产出
推荐引用方式
GB/T 7714
Wang, YT. Reversible transient nucleation in ionic solutions as the precursor of ion crystallization[J]. EPL,2014,107(3):30005.
APA Wang, YT.(2014).Reversible transient nucleation in ionic solutions as the precursor of ion crystallization.EPL,107(3),30005.
MLA Wang, YT."Reversible transient nucleation in ionic solutions as the precursor of ion crystallization".EPL 107.3(2014):30005.

入库方式: OAI收割

来源:理论物理研究所

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