Unraveling the Metabolic Pathway in Leucosceptrum canum by Isolation of New Defensive Leucosceptroid Degradation Products and Biomimetic Model Synthesis
文献类型：期刊论文
| 作者 | Luo, Shi-Hong1; Hugelshofer, Cedric L.2; Hua, Juan1,3; Jing, Shu-Xi1,3; Li, Chun-Huan1; Liu, Yan1; Li, Xiao-Nian1; Zhao, Xu1; Magauer, Thomas2; Li, Sheng-Hong1
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| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2014-12-19 |
| 卷号 | 16期号:24页码:6416-6419 |
| 英文摘要 | Seven new leucosceptroid degradation products possessing a C-20, C-21, or C-25 framework, norleucosceptroids DH (1-5), leucosceptroids P (6), and Q (7), have been isolated from Leucosceptrum canum. Their structures were determined by comprehensive NMR, MS, and single-crystal X-ray diffraction analyses. Discovery of these key intermediates, together with the biomimetic oxidation of a model system, supports the hypothesis that two biosynthetic pathways are operative. Antifeedant activity was observed for compounds 1-3. |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SINGLET-OXYGEN ; ASYMMETRIC-SYNTHESIS ; GLANDULAR TRICHOMES ; NATURAL-PRODUCTS ; SESTERTERPENOIDS ; FURANS ; PHOTOOXYGENATION ; BIOSYNTHESIS ; ARABIDOPSIS ; CHEMISTRY |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000346759900039 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/20418]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China 2.Univ Munich, Dept Chem & Pharm, D-81377 Munich, Germany 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Shi-Hong,Hugelshofer, Cedric L.,Hua, Juan,et al. Unraveling the Metabolic Pathway in Leucosceptrum canum by Isolation of New Defensive Leucosceptroid Degradation Products and Biomimetic Model Synthesis[J]. ORGANIC LETTERS,2014,16(24):6416-6419. |
| APA | Luo, Shi-Hong.,Hugelshofer, Cedric L..,Hua, Juan.,Jing, Shu-Xi.,Li, Chun-Huan.,...&Li, Sheng-Hong.(2014).Unraveling the Metabolic Pathway in Leucosceptrum canum by Isolation of New Defensive Leucosceptroid Degradation Products and Biomimetic Model Synthesis.ORGANIC LETTERS,16(24),6416-6419. |
| MLA | Luo, Shi-Hong,et al."Unraveling the Metabolic Pathway in Leucosceptrum canum by Isolation of New Defensive Leucosceptroid Degradation Products and Biomimetic Model Synthesis".ORGANIC LETTERS 16.24(2014):6416-6419. |
入库方式： OAI收割
来源：昆明植物研究所
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