New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family
文献类型:期刊论文
作者 | Cao, Pei; Yang, Jing![]() ![]() |
刊名 | ORGANIC LETTERS
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出版日期 | 2015-03-06 |
卷号 | 17期号:5页码:1146-1149 |
通讯作者 | Zhao,LX (reprint author),Yunnan Univ,Minist Educ,Key Lab Microbial Resources,Kunming 650091,Peoples R China. ; zlx70@163.com ; sxhuang@mail.kib.ac.cn |
英文摘要 | Duclauxamide A1 (1), a new polyketide-derived heptacyclic oligophenalenone dimer with a N-2-hydroxyethyl moiety, was isolated from Penicillium manginii YIM PH30375. Spectroscopic analysis, X-ray single crystal diffraction, and C-13 NMR DFT calculations confirmed that compound 1 and other duclauxin analogues possess the unified S configuration at C-9', which corrects a long-standing misrepresentation of duclauxins as C-9'R epimers. A plausible biosynthetic pathway for duclauxins is proposed on the basis of previous acetate labeling results for duclauxin and sclerodin. |
学科主题 | Chemistry, Organic |
类目[WOS] | Chemistry, Organic |
研究领域[WOS] | Chemistry |
关键词[WOS] | PANAX-NOTOGINSENG ; NATURAL-PRODUCTS ; FUNGUS ; METABOLITES ; BIOSYNTHESIS ; DELACROIX ; MONOBROMODUCLAUXIN ; MICROORGANISMS ; GENOTOXICITY ; XENOCLAUXIN |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000350841300022 |
源URL | [http://ir.kib.ac.cn/handle/151853/20576] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
推荐引用方式 GB/T 7714 | Cao, Pei,Yang, Jing,Miao, Cui-Ping,et al. New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family[J]. ORGANIC LETTERS,2015,17(5):1146-1149. |
APA | Cao, Pei.,Yang, Jing.,Miao, Cui-Ping.,Yan, Yijun.,Ma, Ya-Tuan.,...&Huang, Sheng-Xiong.(2015).New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family.ORGANIC LETTERS,17(5),1146-1149. |
MLA | Cao, Pei,et al."New Duclauxamide from Penicillium manginii YIM PH30375 and Structure Revision of the Duclauxin Family".ORGANIC LETTERS 17.5(2015):1146-1149. |
入库方式: OAI收割
来源:昆明植物研究所
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