Effective catalysis of poly(ethylene terephthalate) (PET) degradation by metallic acetate ionic liquids
文献类型：期刊论文
| 作者 | Zhou, Xueyuan1,2; Lu, Xingmei1; Wang, Qian1; Zhu, Minli2; Li, Zengxi2 |
| 刊名 | PURE AND APPLIED CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 84期号:3页码:789-801 |
| 关键词 | ionic liquids poly(ethylene terephthalate) (PET) degradation bis(hydroxyethyl terephthalate) (BHET) |
| ISSN号 | 0033-4545 |
| 英文摘要 | Poly(ethylene terephthalate) (PET) is widely used for beverage bottles, electrical and electronic instruments, household wares, and so on. As a consequence of dramatically increasing consumption, recycling of post-consumer PET products has become an important environmental opportunity for sustainable usage in society. In this paper, we investigated the use of chlorine-free metallic acetate ionic liquids (ILs) as catalysts for the degradation of PET because of their lower toxicity, corrosivity, and cost. 1,3-Diethylimidazolium triaceticzincate ([deim][Zn(OAc)(3)]) behaved as the best in this group. The synthesized ILs and the major product, characterized by a variety of techniques and factors affecting glycolysis, were examined. Under optimum conditions, conversion of PET reached 98.05 %, and the selectivity of the bis(hydroxyethyl) terephthalate (BHET) monomer was 70.94 %. A probable mechanism for the glycolysis of PET catalyzed by [deim][Zn(OAc)(3)] was given. In our opinion, catalysis accounted for the synergic effect of the cation and anion of the IL. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SOFT-DRINK BOTTLES ; DIFFERENTIAL SCANNING CALORIMETRY ; UNSATURATED POLYESTER RESINS ; POLYETHYLENE TEREPHTHALATE ; SUPERCRITICAL METHANOL ; THERMAL-DEGRADATION ; ETHYLENE-GLYCOL ; DEPOLYMERIZATION ; WASTE ; HYDROLYSIS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000301282100028 |
| 公开日期 | 2015-07-08 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/16724]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xueyuan,Lu, Xingmei,Wang, Qian,et al. Effective catalysis of poly(ethylene terephthalate) (PET) degradation by metallic acetate ionic liquids[J]. PURE AND APPLIED CHEMISTRY,2012,84(3):789-801. |
| APA | Zhou, Xueyuan,Lu, Xingmei,Wang, Qian,Zhu, Minli,&Li, Zengxi.(2012).Effective catalysis of poly(ethylene terephthalate) (PET) degradation by metallic acetate ionic liquids.PURE AND APPLIED CHEMISTRY,84(3),789-801. |
| MLA | Zhou, Xueyuan,et al."Effective catalysis of poly(ethylene terephthalate) (PET) degradation by metallic acetate ionic liquids".PURE AND APPLIED CHEMISTRY 84.3(2012):789-801. |
入库方式： OAI收割
来源：过程工程研究所
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