Heterocyclic Energetic Salts of 4,4 ',5,5 '-Tetranitro-2,2 '-Biimidazole
文献类型：期刊论文
| 作者 | Liu, Long1; Zhang, Yanqiang1; Zhang, Suojiang1; Fei, Teng2 |
| 刊名 | JOURNAL OF ENERGETIC MATERIALS
 |
| 出版日期 | 2015-07-03 |
| 卷号 | 33期号:3页码:202-214 |
| 关键词 | detonation performance energetic salts high-nitrogen 4 4 ' 5 5 '-tetranitro-2 2 '-biimidazolate |
| ISSN号 | 0737-0652 |
| 英文摘要 | A series of nitrogen-containing heterocyclic 4,4 ',5,5 '-tetranitro-2,2 '-biimidazolate salts was synthesized with the cations as pyridinium (3), pyrazolium (4), 3-amino-pyrazolium (5), imidazolium (6), N-methylimidazolium (7), 1,2,4-triazolium (8), 3-amino-1,2,4-triazolium (9), 3,5-diamino-1,2,4-triazolium (10), 1,2,3-triazolium (11), 1,5-diamino-tetrazolium (12), and 2,2 '-biimidazolium (13). These salts were characterized by nuclear magnetic resonance, infrared spectroscopy, and elemental analysis. Their properties were measured or calculated. Salts 4, 6, 7, 8, and 9 were confirmed by single-crystal X-ray diffraction. Salt 13 with a bicyclic cation has the highest heat of formation of 3.06kJ/g. With the highest detonation performance (29.9GPa, 8,638m/s) and low sensitivity (30J,>360N), salt 12 is a promising candidate as an insensitive explosive. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Engineering ; Materials Science |
| 关键词[WOS] | IONIC LIQUIDS ; TNBI |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000351834100005 |
| 公开日期 | 2015-07-08 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/16730]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 2.Xian Univ Sci & Technol, Sch Chem & Chem Engn, Xian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Long,Zhang, Yanqiang,Zhang, Suojiang,et al. Heterocyclic Energetic Salts of 4,4 ',5,5 '-Tetranitro-2,2 '-Biimidazole[J]. JOURNAL OF ENERGETIC MATERIALS,2015,33(3):202-214. |
| APA | Liu, Long,Zhang, Yanqiang,Zhang, Suojiang,&Fei, Teng.(2015).Heterocyclic Energetic Salts of 4,4 ',5,5 '-Tetranitro-2,2 '-Biimidazole.JOURNAL OF ENERGETIC MATERIALS,33(3),202-214. |
| MLA | Liu, Long,et al."Heterocyclic Energetic Salts of 4,4 ',5,5 '-Tetranitro-2,2 '-Biimidazole".JOURNAL OF ENERGETIC MATERIALS 33.3(2015):202-214. |
入库方式： OAI收割
来源：过程工程研究所
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