中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Removal of sodium (Na2O) from alumina extracted coal fly ash by a mild hydrothermal process

文献类型:期刊论文

作者Li, Huiquan1; Hui, Junbo1,2; Wang, Chenye1; Bao, Weijun1; Sun, Zhenhua1
刊名HYDROMETALLURGY
出版日期2015-03-01
卷号153页码:1-5
关键词Coal fly ash NaCaHSiO4 Sodium removal Hydrothermal process
ISSN号0304-386X
英文摘要Sodium was removed from alumina-extracted coal fly ash (CFA) by using diluted NaOH solution. The effects of reaction temperature, reaction time, and NaOH concentration on sodium removal were studied. Result shows that the sodium (Na2O) content of the alumina-extracted CFA was decreased from 20 wt.% to 0.6 wt.% under optimal conditions: temperature of 185 degrees C, NaOH concentration of 50 g/L, residence time of 2 h, and liquid-to-solid ratio of 40 for water washing. The possible mechanism of sodium removal was also investigated using Fourier transform infrared spectroscopy, X-ray diffraction analysis, and nuclear magnetic resonance spectroscopy. The results indicated that NaCaHSiO4 in the residue was decomposed by NaOH to form NaSiO3 and Ca(OH)(2), and then converted into tobermorite [Ca5Si6O16(OH)(2)center dot nH(2)O] and NaOH. The sodium obtained through the reaction in the residue was mainly combined with the silanol group and then washed with water. (C) 2015 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Technology
类目[WOS]Metallurgy & Metallurgical Engineering
研究领域[WOS]Metallurgy & Metallurgical Engineering
关键词[WOS]C-S-H ; ALKALI
收录类别SCI
语种英语
WOS记录号WOS:000353003600001
公开日期2015-07-08
源URL[http://ir.ipe.ac.cn/handle/122111/16736]  
专题过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Key Lab Green Proc & Engn, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Li, Huiquan,Hui, Junbo,Wang, Chenye,et al. Removal of sodium (Na2O) from alumina extracted coal fly ash by a mild hydrothermal process[J]. HYDROMETALLURGY,2015,153:1-5.
APA Li, Huiquan,Hui, Junbo,Wang, Chenye,Bao, Weijun,&Sun, Zhenhua.(2015).Removal of sodium (Na2O) from alumina extracted coal fly ash by a mild hydrothermal process.HYDROMETALLURGY,153,1-5.
MLA Li, Huiquan,et al."Removal of sodium (Na2O) from alumina extracted coal fly ash by a mild hydrothermal process".HYDROMETALLURGY 153(2015):1-5.

入库方式: OAI收割

来源:过程工程研究所

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