Precipitation of alpha-Fe2O3 and recovery of Ni and Co from synthetic laterite-leaching solutions
文献类型：期刊论文
| 作者 | Zhang, Peiyu1,2; Guo, Qiang1; Wei, Guangye1; Qu, Jingkui1; Qi, Tao1 |
| 刊名 | HYDROMETALLURGY
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 153页码:21-29 |
| 关键词 | Laterite-leaching solutions Hydrolysis Recovery of Ni and Co Growth model of alpha-Fe2O3 |
| ISSN号 | 0304-386X |
| 英文摘要 | Atmospheric hydrochloric-acid leaching of nickel laterite can produce a leaching solution containing a large amount of Fe. To recover Ni and Co, Fe should be separated from the laterite-leaching solutions. In this study, hydrolytic distillation was used to remove Fe from the synthetic laterite-leaching solutions; Ni and Co remained as soluble chlorides in the solutions, while most Fe was removed as Fe2O3. The conversion of Fe, recovery of Ni and Co, recovery of HCI, and the concentration of HCI, were investigated under various conditions. The results showed that the optimal output was obtained under the following process conditions: the hydrolysis temperature was 170 degrees C, the pressure was 0.03 MPa, the water flow rate was 1.67 mL/min, and the hydrolysis duration was 2 h. The effects of impurities under the optimized conditions were also studied, showing that as the amount of metal chlorides increased, the conversion of Fe decreased. The residues were characterized by X-ray diffraction analysis and scanning electron microscopy with X-ray energy-dispersive spectroscopy. Using the results, a growth model of alpha-Fe2O3 (hematite) spheres from the synthetic laterite-leaching solutions was constructed. (C) 2015 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Metallurgy & Metallurgical Engineering |
| 研究领域[WOS] | Metallurgy & Metallurgical Engineering |
| 关键词[WOS] | FORCED HYDROLYSIS ; FECL3 SOLUTIONS ; FORMATION MECHANISM ; LIMONITIC LATERITE ; HEMATITE PARTICLES ; HYDROCHLORIC-ACID ; GOETHITE ; CHLORIDE ; IRON ; MICROSTRUCTURE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000353003600004 |
| 公开日期 | 2015-07-08 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/16743]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Peiyu,Guo, Qiang,Wei, Guangye,et al. Precipitation of alpha-Fe2O3 and recovery of Ni and Co from synthetic laterite-leaching solutions[J]. HYDROMETALLURGY,2015,153:21-29. |
| APA | Zhang, Peiyu,Guo, Qiang,Wei, Guangye,Qu, Jingkui,&Qi, Tao.(2015).Precipitation of alpha-Fe2O3 and recovery of Ni and Co from synthetic laterite-leaching solutions.HYDROMETALLURGY,153,21-29. |
| MLA | Zhang, Peiyu,et al."Precipitation of alpha-Fe2O3 and recovery of Ni and Co from synthetic laterite-leaching solutions".HYDROMETALLURGY 153(2015):21-29. |
入库方式： OAI收割
来源：过程工程研究所
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