Kinetics and mechanism study on catalytic oxidation of chlorobenzene over V2O5/TiO2 catalysts
文献类型：期刊论文
| 作者 | Wang, Jian1,2; Wang, Xue1; Liu, Xiaolong1; Zeng, Junlin1,3; Guo, Yangyang1; Zhu, Tingyu1 |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 402页码:1-9 |
| 关键词 | Catalytic oxidation Chlorobenzene Chlorinated benzenes V2O5/TiO2 FTIR |
| ISSN号 | 1381-1169 |
| 英文摘要 | In this article, we present a detailed study combining the kinetic studies and in-situ FTIR experiments to investigate the oxidation behavior of chlorobenzene over V2O5/TiO2 catalysts. The catalytic data show the 3-5 wt.% V2O5/TiO2 catalysts are best fit for the oxidation of chlorobenzene. The calculated apparent reaction orders are about 0.6 and 0.2, respectively. The results of in-situ FTIR provided mechanism insights into the catalytic reaction, which supports the following proposal: (i) a nucleophilic substitution on V=O species and (ii) attacking by surface oxygen through a electrophilic substitution, then (iii) followed by the cracking of ring structure, and further oxidation of the resulting species to form final products. The above results further suggest that the nucleophilic substitution process and surface reaction are kinetically significant steps for chlorobenzene oxidation, determining the overall rate of the reaction. Furthermore, 1,2-dichlorobenzene, 1,3-dichlorobenzene and 1,2,4-trichlorobenzene as additional reactants were tested together with chlorobenzene in binary mixtures to examine their competition reactions. (C) 2015 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ALTERNATIVE SCR CATALYSTS ; VANADIA-TITANIA CATALYSTS ; OXIDE-BASED FORMULATIONS ; IN-SITU FTIR ; CHLORINATED BENZENES ; ACTIVATED CARBON ; NITRIC-OXIDE ; ADSORPTION ; REDUCTION ; 1,2-DICHLOROBENZENE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000353600500001 |
| 公开日期 | 2015-07-08 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/16754]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Res Ctr Proc Pollut Control, Natl Engn Lab Hydromet Cleaner Prod Technol, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Guizhou Univ, Chem & Chem Engn, Guiyang 550025, Guizhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jian,Wang, Xue,Liu, Xiaolong,et al. Kinetics and mechanism study on catalytic oxidation of chlorobenzene over V2O5/TiO2 catalysts[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2015,402:1-9. |
| APA | Wang, Jian,Wang, Xue,Liu, Xiaolong,Zeng, Junlin,Guo, Yangyang,&Zhu, Tingyu.(2015).Kinetics and mechanism study on catalytic oxidation of chlorobenzene over V2O5/TiO2 catalysts.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,402,1-9. |
| MLA | Wang, Jian,et al."Kinetics and mechanism study on catalytic oxidation of chlorobenzene over V2O5/TiO2 catalysts".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 402(2015):1-9. |
入库方式： OAI收割
来源：过程工程研究所
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