One-pot controllable synthesis of oligo(carbonate-ether) triol using a Zn-Co-DMC catalyst: the special role of trimesic acid as an initiation-transfer agent
文献类型：期刊论文
| 作者 | Liu, Shunjie ; Qin, Yusheng ; Chen, Xuesi ; Wang ; Xianhong ; Wang,Fosong |
| 刊名 | polymer chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 5期号:21页码:6171-6179 |
| 关键词 | METAL-CYANIDE COMPLEX RING-OPENING POLYMERIZATION CO2/PROPYLENE OXIDE COPOLYMERIZATION HIGH-MOLECULAR-WEIGHT CARBON-DIOXIDE PROPYLENE-OXIDE CYCLOHEXENE OXIDE POLY(PROPYLENE CARBONATE) ALTERNATING COPOLYMERIZATION SALEN COMPLEXES |
| 通讯作者 | qin,ys |
| 英文摘要 | a one-pot synthesis of oligo(carbonate-ether) triol was realized by the copolymerization of co2 and propylene oxide (po) using a zinc-cobalt double metal cyanide (zn-co-dmc) catalyst in the presence of 1,3,5-benzenetricarboxylic (trimesic) acid (tma). the catalytic activity ranged from 0.3 to 1.0 kg g(-1) dmc under various copolymerization conditions. the structure of the oligo(carbonate-ether) triol was clearly confirmed, providing sound evidence for the special role played by the tma, i.e., that it acted as an initiation-transfer agent. in the first stage the tma initiated po homo-polymerization to afford oligo-ether triol via a core-first approach in the presence of zn-co-dmc. after all of the tma was consumed, the in situ formed oligo-ether triol acted as new chain transfer agent to participate in the copolymerization, forming carbonate-ether segments and therefore the oligo(carbonate-ether) triol. since every molecule of tma participated in initiation and propagation steps, the molecular weight of the triol depended on the amount of tma used rather than the amount of zn-co-dmc. consequently, the number average molecular weight (m-n) of the oligo(carbonate-ether) triol could be well controlled from 1400 to 3800 g mol(-1) with a relatively narrow polydispersity index (pdi) (1.15-1.45), and its carbonate unit content (cu) could be adjusted between 20% and 54%. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000342761200006 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/53006]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu, Shunjie,Qin, Yusheng,Chen, Xuesi,et al. One-pot controllable synthesis of oligo(carbonate-ether) triol using a Zn-Co-DMC catalyst: the special role of trimesic acid as an initiation-transfer agent[J]. polymer chemistry,2014,5(21):6171-6179. |
| APA | Liu, Shunjie,Qin, Yusheng,Chen, Xuesi,Wang,Xianhong,&Wang,Fosong.(2014).One-pot controllable synthesis of oligo(carbonate-ether) triol using a Zn-Co-DMC catalyst: the special role of trimesic acid as an initiation-transfer agent.polymer chemistry,5(21),6171-6179. |
| MLA | Liu, Shunjie,et al."One-pot controllable synthesis of oligo(carbonate-ether) triol using a Zn-Co-DMC catalyst: the special role of trimesic acid as an initiation-transfer agent".polymer chemistry 5.21(2014):6171-6179. |
入库方式： OAI收割
来源：长春应用化学研究所
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