Synthesis of high-silica EU-1 zeolite in the presence of hexamethonium ions: A seeded approach for inhibiting ZSM-48
文献类型：期刊论文
| 作者 | Xu, Qinghu1; Gong, Yanjun1; Xu, Wenjing1; Xu, Jun2; Deng, Feng2; Dou, Tao1 |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2011-06-01 |
| 卷号 | 358期号:1页码:252-260 |
| 关键词 | High-silica EU-1 Seeded synthesis Hexamethonium bromide ZSM-48 |
| 产权排序 | 第二 |
| 通讯作者 | Dou,T |
| 英文摘要 | A seeded approach was developed to synthesize high-silica EU-1 zeolite via inhibiting the co-crystallization of ZSM-48 in the presence of hexamethonium (HM) ions. A systematic study was carried out to determine factors such as seed content and SiO2/Al2O3 ratio, which influenced the crystallization of high-silica EU-1 and transformation of EU-1 into ZSM-48. Using EU-1 seeds, not only well-crystallized pure EU-1 zeolites with SiO2/Al2O3 ratios more than 500 were synthesized, but also the co-crystalline of ZSM-48/EU-1 or pure ZSM-48 was obtained in control from silica-rich mixture gels. Furthermore, the kinetic features of the seeded synthesis of EU-1 zeolites with SiO2/Al2O3 ratios of 55, 190, and 500 were examined. It was found that seeds played crucial roles in the decrease of apparent activation energy of EU-1 nucleation and inhibiting the transformation of EU-1 into ZSM-48. The HM and Al species performed synergistic roles to inhibit the formation ZSM-48 during high-silica EU-1 nucleation and crystal growth. (C) 2011 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | 波谱分析 |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HYDROTHERMAL SYNTHESIS ; DIRECTING AGENT ; CRYSTALLIZATION ; MECHANISM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000289600300034 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1780]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.China Univ Petr, China Natl Petr Corp, Key Lab Catalysis, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Qinghu,Gong, Yanjun,Xu, Wenjing,et al. Synthesis of high-silica EU-1 zeolite in the presence of hexamethonium ions: A seeded approach for inhibiting ZSM-48[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2011,358(1):252-260. |
| APA | Xu, Qinghu,Gong, Yanjun,Xu, Wenjing,Xu, Jun,Deng, Feng,&Dou, Tao.(2011).Synthesis of high-silica EU-1 zeolite in the presence of hexamethonium ions: A seeded approach for inhibiting ZSM-48.JOURNAL OF COLLOID AND INTERFACE SCIENCE,358(1),252-260. |
| MLA | Xu, Qinghu,et al."Synthesis of high-silica EU-1 zeolite in the presence of hexamethonium ions: A seeded approach for inhibiting ZSM-48".JOURNAL OF COLLOID AND INTERFACE SCIENCE 358.1(2011):252-260. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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