Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy
文献类型：期刊论文
| 作者 | Qin, Chaochao1,2,3,4; Tzeng, Sheng Yuan1,2; Zhang, Bing3; Tzeng, Wen Bih1,2 |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2011-02-08 |
| 卷号 | 503期号:1-3页码:25-28 |
| 产权排序 | 第三 |
| 通讯作者 | Tzeng,WB |
| 英文摘要 | We applied the two-color resonant two-photon ionization and mass-analyzed threshold ionization techniques to investigate the ionic properties of the selected rotamers of p-methoxystyrene. The adiabatic ionization energies of cis- and trans-p-methoxystyrene are determined to be 62 487 +/- 5 and 62 512 +/- 5 cm (1), respectively. Most of the observed active vibrations involve in-plane ring and substituent-sensitive motions. Our experimental results show that different orientation of the methoxyl group with respect to the vinyl group only slightly influence these cation vibrations, depending on the degree of involvement of the substituents involved in the overall vibrations. (C) 2011 Elsevier B. V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 学科主题 | 原子分子物理学 |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | ROTATIONAL ISOMERS ; CATION ; ENERGY ; ZEKE ; FLUORESCENCE ; DYNAMICS ; JET |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000286976700004 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1819]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 2.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan 3.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Chaochao,Tzeng, Sheng Yuan,Zhang, Bing,et al. Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy[J]. CHEMICAL PHYSICS LETTERS,2011,503(1-3):25-28. |
| APA | Qin, Chaochao,Tzeng, Sheng Yuan,Zhang, Bing,&Tzeng, Wen Bih.(2011).Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy.CHEMICAL PHYSICS LETTERS,503(1-3),25-28. |
| MLA | Qin, Chaochao,et al."Selected cis- and trans-p-methoxystyrene rotamers studied by mass-analyzed threshold ionization spectroscopy".CHEMICAL PHYSICS LETTERS 503.1-3(2011):25-28. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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