Hollow mesoporous aluminosilicate spheres with acidic shell
文献类型：期刊论文
| 作者 | Li, Junhua1,2; Zhang, Dan2; Gao, Qiang1,4; Xu, Yao1; Wu, Dong1; Sun, Yuhan1; Xu, Jun3; Deng, Feng3 |
| 刊名 | MATERIALS CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2011 |
| 卷号 | 125期号:1-2页码:286-292 |
| 关键词 | Mesoporous silica Zeolite precursors Catalytic cracking |
| 产权排序 | 第三 |
| 英文摘要 | Hollow mesoporous aluminosilicate spheres (HMAS) with middle strong acidity have been successfully synthesized by simply hydrothermally treating mesoporous silica spheres (MSS) in zeolite precursor solution. Based on a set of time-dependent experiments, it was found that the hollowing process was associated with a progressive mass redistribution and changes of pores structures. The surfactant cetyltrimethylammonium bromide (CTAB) located in the pores of MSS protected the mesoporous silica spheres from dissolving into strongly basic zeolite precursor solution and acted as the template for mesoporous shell. Under the templating function of CTAB, primary zeolite units were introduced into the mesopore walls of HMAS. The acidity of the resultant samples HMAS was measured by NH(3)-TPD techniques. Catalytic tests showed that the HMAS catalysts exhibited high catalytic activity compared with the MSS and H beta zeolite for catalytic cracking of 1,3,5-triisopropylbenzene. (C) 2010 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 学科主题 | 数学 |
| 类目[WOS] | Materials Science, Multidisciplinary |
| 研究领域[WOS] | Materials Science |
| 关键词[WOS] | SILICA SPHERES ; ZEOLITE-BETA ; NANOSTRUCTURED SILICA ; NAALO2 SOLUTION ; MSU-S ; NANOPARTICLES ; STABILITY ; PROPERTY ; MESOSTRUCTURES ; MICROSPHERES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000285285100048 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1882]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Liaoning Univ Technol, Sch Chem & Environm Engn, Jinzhou 121001, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Junhua,Zhang, Dan,Gao, Qiang,et al. Hollow mesoporous aluminosilicate spheres with acidic shell[J]. MATERIALS CHEMISTRY AND PHYSICS,2011,125(1-2):286-292. |
| APA | Li, Junhua.,Zhang, Dan.,Gao, Qiang.,Xu, Yao.,Wu, Dong.,...&Deng, Feng.(2011).Hollow mesoporous aluminosilicate spheres with acidic shell.MATERIALS CHEMISTRY AND PHYSICS,125(1-2),286-292. |
| MLA | Li, Junhua,et al."Hollow mesoporous aluminosilicate spheres with acidic shell".MATERIALS CHEMISTRY AND PHYSICS 125.1-2(2011):286-292. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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