Two W/Mo complexes containing 2,3-dihydroxynaphthalene: synthesis and structure analysis
文献类型：期刊论文
| 作者 | Yu,C ; Shi,XD ; Chi,ZX ; Bi,YG ; Chen,YY ; Ye,CH ; Lu,XM |
| 刊名 | JOURNAL OF COORDINATION CHEMISTRY
 |
| 出版日期 | 2011 |
| 卷号 | 64期号:14页码:2521-2530 |
| 产权排序 | 第二 |
| 英文摘要 | Two W/Mo complexes, [Et(3)NH](2)[WO(2)(C(10)H(6)O(2))(2)] (1) and [Et(3)NH](2)[MoO(2)(C(10)H(6)O(2))(2)] (2), were synthesized by the reaction of Na(2)WO(4) center dot 2H(2)O and (NH(4))(2)Mo(2)O(7) center dot 4H(2)O with 2,3-DHN (DHN = dihydroxynaphthalene) and triethylamine, and characterized by X-ray diffraction and IR. The two complexes exhibit chiral octahedral geometry at central metals, although the overall structure is racemic. Single crystals of 1 are more difficult to obtain than for 2. The molybdenum complex can be easily isolated at room temperature (around 25 degrees C), while the tungsten one needs to be isolated under 15 degrees C, otherwise, the quality of crystal will be poor, leading to disorder. The structures of these two complexes are chiral and enantiomorphous to each other. |
| 学科主题 | 波谱学 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1914]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 推荐引用方式 GB/T 7714 | Yu,C,Shi,XD,Chi,ZX,et al. Two W/Mo complexes containing 2,3-dihydroxynaphthalene: synthesis and structure analysis[J]. JOURNAL OF COORDINATION CHEMISTRY,2011,64(14):2521-2530. |
| APA | Yu,C.,Shi,XD.,Chi,ZX.,Bi,YG.,Chen,YY.,...&Lu,XM.(2011).Two W/Mo complexes containing 2,3-dihydroxynaphthalene: synthesis and structure analysis.JOURNAL OF COORDINATION CHEMISTRY,64(14),2521-2530. |
| MLA | Yu,C,et al."Two W/Mo complexes containing 2,3-dihydroxynaphthalene: synthesis and structure analysis".JOURNAL OF COORDINATION CHEMISTRY 64.14(2011):2521-2530. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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