A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate
文献类型:期刊论文
作者 | Shen, Wanling1; Li, Shenhui1; Xu, Jun1; Zhang, Hailu1; Hu, Wei1; Zhou, Dan2; Zhang, Jianan2; Yu, Jihong2,3; Xu, Wujun3; Xu, Yao3 |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
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出版日期 | 2010-04-22 |
卷号 | 114期号:15页码:7076-7084 |
产权排序 | 第一 |
英文摘要 | A novel phase transformation phenomenon that involves two successive phase transformation events was found for the first time in the synthesis of mesostructured aluminophosphate and studied by XRD, TEM, and multinuclear solid-state NMR techniques. The results showed that a hexagonal phase Hex and two lamellar phases, L1 and L2, were formed after hydrothermal treatment for 1, 3, and 50 h, respectively. The status of the surfactant was found to be arrayed interdigitatecl in a bilayer with a tilt angle in L1 phase but upright in L2 phase. A mechanism that the exciting of the alkane tail of the surfactant together with the condensation of aluminophosphate cooperatively promoted the phase transformation was proposed for the observed phenomenon. Additionally, a ZON microporous structure was found for the first time existing in the framework of the mesostructured aluminophosphate. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
学科主题 | 波谱分析 |
类目[WOS] | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
关键词[WOS] | SOLID-STATE NMR ; MOLECULAR-SIEVE SYNTHESIS ; CRYSTALLINE INORGANIC SOLIDS ; IN-SITU SAXS ; SILICA/SURFACTANT COMPOSITES ; GEL PHASES ; MQMAS NMR ; SURFACTANT ; INTERMEDIATE ; SPECTROSCOPY |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000276562500029 |
源URL | [http://ir.wipm.ac.cn/handle/112942/1969] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 3.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China |
推荐引用方式 GB/T 7714 | Shen, Wanling,Li, Shenhui,Xu, Jun,et al. A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2010,114(15):7076-7084. |
APA | Shen, Wanling.,Li, Shenhui.,Xu, Jun.,Zhang, Hailu.,Hu, Wei.,...&Deng, Feng.(2010).A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate.JOURNAL OF PHYSICAL CHEMISTRY C,114(15),7076-7084. |
MLA | Shen, Wanling,et al."A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate".JOURNAL OF PHYSICAL CHEMISTRY C 114.15(2010):7076-7084. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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