中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate

文献类型:期刊论文

作者Shen, Wanling1; Li, Shenhui1; Xu, Jun1; Zhang, Hailu1; Hu, Wei1; Zhou, Dan2; Zhang, Jianan2; Yu, Jihong2,3; Xu, Wujun3; Xu, Yao3
刊名JOURNAL OF PHYSICAL CHEMISTRY C
出版日期2010-04-22
卷号114期号:15页码:7076-7084
产权排序第一
英文摘要A novel phase transformation phenomenon that involves two successive phase transformation events was found for the first time in the synthesis of mesostructured aluminophosphate and studied by XRD, TEM, and multinuclear solid-state NMR techniques. The results showed that a hexagonal phase Hex and two lamellar phases, L1 and L2, were formed after hydrothermal treatment for 1, 3, and 50 h, respectively. The status of the surfactant was found to be arrayed interdigitatecl in a bilayer with a tilt angle in L1 phase but upright in L2 phase. A mechanism that the exciting of the alkane tail of the surfactant together with the condensation of aluminophosphate cooperatively promoted the phase transformation was proposed for the observed phenomenon. Additionally, a ZON microporous structure was found for the first time existing in the framework of the mesostructured aluminophosphate.
WOS标题词Science & Technology ; Physical Sciences ; Technology
学科主题波谱分析
类目[WOS]Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]SOLID-STATE NMR ; MOLECULAR-SIEVE SYNTHESIS ; CRYSTALLINE INORGANIC SOLIDS ; IN-SITU SAXS ; SILICA/SURFACTANT COMPOSITES ; GEL PHASES ; MQMAS NMR ; SURFACTANT ; INTERMEDIATE ; SPECTROSCOPY
收录类别SCI
语种英语
WOS记录号WOS:000276562500029
源URL[http://ir.wipm.ac.cn/handle/112942/1969]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
2.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
3.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
推荐引用方式
GB/T 7714
Shen, Wanling,Li, Shenhui,Xu, Jun,et al. A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2010,114(15):7076-7084.
APA Shen, Wanling.,Li, Shenhui.,Xu, Jun.,Zhang, Hailu.,Hu, Wei.,...&Deng, Feng.(2010).A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate.JOURNAL OF PHYSICAL CHEMISTRY C,114(15),7076-7084.
MLA Shen, Wanling,et al."A Novel Phase Transformation Phenomenon in Mesostructured Aluminophosphate".JOURNAL OF PHYSICAL CHEMISTRY C 114.15(2010):7076-7084.

入库方式: OAI收割

来源:武汉物理与数学研究所

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