Mass-analyzed Threshold Ionization Spectroscopy of Rotamers of p-ethoxyphenol Cations and Configuration Effect
文献类型：期刊论文
| 作者 | Zheng, Qiu-sha1,2,3; Fang, Teng I.1; Zhang, Bing2; Tzeng, Wen Bih1 |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2009-12-27 |
| 卷号 | 22期号:6页码:649-654 |
| 关键词 | Mass-analyzed threshold ionization spectroscopy p-ethoxyphenol Cation Vibration |
| 通讯作者 | Tzeng, WB (reprint author), Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan. |
| 英文摘要 | Two-color resonant two-photon mass-analyzed threshold ionization (MATI) spectroscopy was used to record the vibrationally resolved cation spectra of the selected rotamers of p-ethoxyphenol. The adiabatic ionization energies of the trans and cis rotamers are determined to be 61565+/-5 and 61670+/-5 cm(-1), which are less than that of p-methoxyphenol by 645 and 643 cm(-1), respectively. Analysis on the MATI spectra of the selected rotamers of p-ethoxyphenol cation shows that the relative orientation of the ethoxy group has little effect on the in-plane ring vibrations. The low-frequency OC(2)H(5) bending vibrations appear to be active for both forms of the cation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Physics |
| 关键词[WOS] | HOLE-BURNING SPECTROSCOPY ; SUPERSONIC JET ; SPECTRA ; ENERGY ; HYDROQUINONE ; EXCITATION ; PHENOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000273466600016 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/2138]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Qiu-sha,Fang, Teng I.,Zhang, Bing,et al. Mass-analyzed Threshold Ionization Spectroscopy of Rotamers of p-ethoxyphenol Cations and Configuration Effect[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2009,22(6):649-654. |
| APA | Zheng, Qiu-sha,Fang, Teng I.,Zhang, Bing,&Tzeng, Wen Bih.(2009).Mass-analyzed Threshold Ionization Spectroscopy of Rotamers of p-ethoxyphenol Cations and Configuration Effect.CHINESE JOURNAL OF CHEMICAL PHYSICS,22(6),649-654. |
| MLA | Zheng, Qiu-sha,et al."Mass-analyzed Threshold Ionization Spectroscopy of Rotamers of p-ethoxyphenol Cations and Configuration Effect".CHINESE JOURNAL OF CHEMICAL PHYSICS 22.6(2009):649-654. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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