Photodissociation of iodocyclohexane at 266 and 277 nm: Energy partitioning and curve crossing analysis
文献类型：期刊论文
| 作者 | Zhang, Rongrong1,2; Ghazal, Ahmed Yousif1,2; Liu, Yuzhu1,2; Zhang, Yan1,2; Tang, Bifeng3; Zhang, Bing1,2 |
| 刊名 | OPTICS COMMUNICATIONS
 |
| 出版日期 | 2009-06-01 |
| 卷号 | 282期号:11页码:2169-2173 |
| 关键词 | Iodocyclohexane Photodissociation Ion imaging Curve crossing |
| 通讯作者 | Zhang, B (reprint author), Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China. |
| 英文摘要 | The photodissociation dynamics of iodocyclohexane (C(6)H(11)I) at 266 and 277 nm has been investigated by ion velocity imaging technique. The velocity distributions, angular distributions and relative quantum yields are obtained for 1 ((2)P(3/2)) (denoted 1) and 1 ((2)p(1/2)) (denoted 1*) fragments. The energy partitioning shows that about 70% of the available energy goes into the internal excitation of the photofragments for both dissociation channels. From the angular distributions, we found the value of the anisotropy parameter beta for 1* at the corresponding excitation wavelength was less than that for 1. Based on the measured angular distributions and relative quantum yields, the relative fractions of each excited state to the products are determined. The curve crossing probabilities between the (3)Q(0) and (1)Q(1) states are determined 0.503 at 266 nm and 0.443 at 277 nm. (C) 2009 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Optics |
| 研究领域[WOS] | Optics |
| 关键词[WOS] | PHOTOFRAGMENT TRANSLATIONAL SPECTROSCOPY ; FLIGHT MASS-SPECTROMETRY ; MOLECULAR-BEAM ; CH3I ; DISTRIBUTIONS ; IODIDE ; CF3I ; DEPENDENCE ; DYNAMICS ; SPECTRA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265718600013 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/2215]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Xiaogan Univ, Dept Phys, Xiaogan City 432000, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Rongrong,Ghazal, Ahmed Yousif,Liu, Yuzhu,et al. Photodissociation of iodocyclohexane at 266 and 277 nm: Energy partitioning and curve crossing analysis[J]. OPTICS COMMUNICATIONS,2009,282(11):2169-2173. |
| APA | Zhang, Rongrong,Ghazal, Ahmed Yousif,Liu, Yuzhu,Zhang, Yan,Tang, Bifeng,&Zhang, Bing.(2009).Photodissociation of iodocyclohexane at 266 and 277 nm: Energy partitioning and curve crossing analysis.OPTICS COMMUNICATIONS,282(11),2169-2173. |
| MLA | Zhang, Rongrong,et al."Photodissociation of iodocyclohexane at 266 and 277 nm: Energy partitioning and curve crossing analysis".OPTICS COMMUNICATIONS 282.11(2009):2169-2173. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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