Chiral self-discrimination of the enantiomers of alpha-phenylethylamine derivatives in proton NMR
文献类型：期刊论文
| 作者 | Huang, Shao-Hua1,2; Bai, Zheng-Wu3; Feng, Ji-Wen1 |
| 刊名 | MAGNETIC RESONANCE IN CHEMISTRY
 |
| 出版日期 | 2009-05-01 |
| 卷号 | 47期号:5页码:423-427 |
| 关键词 | NMR (1)H NMR enantiomer chiral self-discrimination hydrogen-bonding interaction |
| 通讯作者 | Feng, JW (reprint author), Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China. |
| 英文摘要 | Two types of chiral analytes, the urea and amide derivatives of cc-phenylethylamine, were prepared. The effect of intermolecular hydrogen-bonding interaction on self-discrimination of the enantiomers of analytes has been investigated using high-resolution (1)H NMR. It was found that the urea derivatives with double-hydrogen-bonding interaction exhibit not only the stronger hydrogen-bonding interaction but also better self-recognition abilities than the amide derivatives (except for one bearing two NO(2) groups). The present results suggest that double-hydrogen-bonding interaction promotes the self-discrimination ability of the chiral compounds. Copyright (C) 2009 John Wiley & Sons, Ltd. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Chemistry, Physical ; Spectroscopy |
| 研究领域[WOS] | Chemistry ; Spectroscopy |
| 关键词[WOS] | SOLUTE-SOLUTE INTERACTIONS ; CARBOXYLIC-ACIDS ; SOLVATING AGENTS ; NONEQUIVALENCE ; SPECTROSCOPY ; RECOGNITION ; ASSOCIATION ; AUXILIARIES ; ALCOHOLS ; PURITY |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000265588100006 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/2230]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Wuhan Inst Technol, Sch Chem Engn & Pharm, Wuhan 430073, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Shao-Hua,Bai, Zheng-Wu,Feng, Ji-Wen. Chiral self-discrimination of the enantiomers of alpha-phenylethylamine derivatives in proton NMR[J]. MAGNETIC RESONANCE IN CHEMISTRY,2009,47(5):423-427. |
| APA | Huang, Shao-Hua,Bai, Zheng-Wu,&Feng, Ji-Wen.(2009).Chiral self-discrimination of the enantiomers of alpha-phenylethylamine derivatives in proton NMR.MAGNETIC RESONANCE IN CHEMISTRY,47(5),423-427. |
| MLA | Huang, Shao-Hua,et al."Chiral self-discrimination of the enantiomers of alpha-phenylethylamine derivatives in proton NMR".MAGNETIC RESONANCE IN CHEMISTRY 47.5(2009):423-427. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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