Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates
文献类型：期刊论文
| 作者 | Chen, Peng1; Li, Jiyang1; Xu, Jun2; Duan, Fangzheng1; Deng, Feng2; Xu, Ruren1 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2009-03-01 |
| 卷号 | 11期号:3页码:622-627 |
| 关键词 | Aluminophosphate Monomer H-bond NMR Solvothermal synthesis Cobalt complex |
| 通讯作者 | Li, JY (reprint author), Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China. |
| 英文摘要 | A new zero-dimensional (0D) aluminophosphate monomer [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)] (H3PO4)(4) (designated AlPO-CJ38) with Al/P ratio of 1/6 has been solvothermally prepared by using racemic cobalt complex dl-Co(en)(3)Cl-3 as the template. The Al atom is octahedrally linked to six P atoms via bridging oxygen atoms, forming a unique [Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](6-) monomer. Notably, there exists intramolecular symmetrical O center dot center dot center dot H center dot center dot center dot O bonds, which results in pseudo-4-rings stabilized by the strong H-bonding interactions. The structure is also featured by the existence of four different types of monophosphates that have been confirmed by P-31 NMR and H-1 NMR spectra. The crystal data are as follows: AlPO-CJ38, [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4), M = 1476.33, monoclinic, C2/c (No. 15), a = 36.028(7) angstrom, b = 8.9877(18) angstrom, c = 16.006(3) angstrom, beta = 100.68(3)degrees, U = 5093.2(18) angstrom(3), Z = 4, R-1 = 0.0509 (I > 2 sigma(I)) and wR(2) = 0.1074 (all data). CCDC number 689491. (C) 2008 Elsevier Masson SAS. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Physics, Condensed Matter |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | OPEN FRAMEWORK ALUMINOPHOSPHATE ; NEUTRON-DIFFRACTION ; HYDROGEN-BOND ; ALUMINUM PHOSPHATE ; CRYSTAL-STRUCTURES ; X-RAY ; LAYERED ALUMINOPHOSPHATE ; METAL PHOSPHATES ; MOLECULAR-SIEVE ; COMPLEX CATIONS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000264644800004 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/2267]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Peng,Li, Jiyang,Xu, Jun,et al. Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates[J]. SOLID STATE SCIENCES,2009,11(3):622-627. |
| APA | Chen, Peng,Li, Jiyang,Xu, Jun,Duan, Fangzheng,Deng, Feng,&Xu, Ruren.(2009).Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates.SOLID STATE SCIENCES,11(3),622-627. |
| MLA | Chen, Peng,et al."Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)(3)](2)[Al(HPO4)(2)(H1.5PO4)(2)(H2PO4)(2)](H3PO4)(4) containing four different types of monophosphates".SOLID STATE SCIENCES 11.3(2009):622-627. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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