Inorganic molecular imprinted titanium dioxide photocatalyst: synthesis, characterization and its application for efficient and selective degradation of phthalate esters
文献类型：期刊论文
| 作者 | Shen, Xiantao1; Zhu, Lihua1; Huang, Chuixiu1; Tang, Heqing1; Yu, Zhiwu2; Deng, Feng2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY
 |
| 出版日期 | 2009 |
| 卷号 | 19期号:27页码:4843-4851 |
| 通讯作者 | Zhu, LH (reprint author), Huazhong Univ Sci & Technol, Coll Chem & Chem Engn, Wuhan 430074, Peoples R China. |
| 英文摘要 | An inorganic molecular imprinted polymer (IMIP) coated photocatalyst for photodegradation of diethyl phthalate (DEP) was synthesized by coating a layer of molecular imprinted silica/alumina on the surface of TiO(2) nanoparticles with DEP as the template. The characterization with HR-TEM, XRD, FT-IR and UV-visible spectroscopic analysis indicated that the new catalyst was a composite of the TiO2 particle core and a shell layer of Al(3+)-doped silica with thickness of about 5 nm. The (27)Al MAS NMR measurements revealed that the IMIP layer consisted of framework tetrahedrally coordinated aluminium and non-framework octa-coordinated aluminium species, both of which function as the hot spots for the adsorption of target molecules on the catalyst during photocatalysis. It was found that the IMIP layer provided the photocatalyst with molecular recognition ability, leading to selective adsorption and rapid mineralization of the target pollutant from its low level solution (2 mg L(-1)) in the presence of other high level non-target pollutants, such as phenol (50 mg L(-1)). Unlike the neat TiO(2) photocatalyst (Degussa P25), the use of the IMIP-coated TiO(2) photocatalyst almost eliminated the generation of toxic aromatic byproducts. Moreover, the new photocatalyst was totally constructed by inorganic compounds, being resistant to photochemical attack and showing favorable lifetime during the photocatalysis. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Materials Science |
| 关键词[WOS] | FOOTPRINT CATALYSIS ; TIO2 PHOTOCATALYSTS ; WATER-TREATMENT ; CAVITIES ; SURFACE ; SILICA ; NANOPARTICLES ; ZEOLITES ; ACID ; TRANSFORMATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000267571800024 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/2295]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Coll Chem & Chem Engn, Wuhan 430074, Peoples R China 2.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Xiantao,Zhu, Lihua,Huang, Chuixiu,et al. Inorganic molecular imprinted titanium dioxide photocatalyst: synthesis, characterization and its application for efficient and selective degradation of phthalate esters[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(27):4843-4851. |
| APA | Shen, Xiantao,Zhu, Lihua,Huang, Chuixiu,Tang, Heqing,Yu, Zhiwu,&Deng, Feng.(2009).Inorganic molecular imprinted titanium dioxide photocatalyst: synthesis, characterization and its application for efficient and selective degradation of phthalate esters.JOURNAL OF MATERIALS CHEMISTRY,19(27),4843-4851. |
| MLA | Shen, Xiantao,et al."Inorganic molecular imprinted titanium dioxide photocatalyst: synthesis, characterization and its application for efficient and selective degradation of phthalate esters".JOURNAL OF MATERIALS CHEMISTRY 19.27(2009):4843-4851. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。