中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A Reaction-Based Colorimetric Fluoride Probe: Rapid "Naked-Eye" Detection and Large Absorption Shift

文献类型:期刊论文

作者Cheng, Xiaohong1; Li, Shuang1; Xu, Guohua2; Li, Conggang2; Qin, Jingui1; Li, Zhen1
刊名CHEMPLUSCHEM
出版日期2012-10-01
卷号77期号:10页码:908-913
关键词azobenzenes charge transfer colorimetric probe fluorides sensors
英文摘要Taking advantage of both the well-known azobenzene structure and the special fluoride-promoted cleavage reaction of the Si?O bond, a new ratiometric colorimetric probe (F-1) toward the fluoride anion was designed and synthesized by using intramolecular charge transfer (ICT) as a signal mechanism. Upon the addition of F- ions, the probe displayed apparent color changes from colorless to deep blue, with a dramatic shift of the maximum absorption wavelength (similar to 230 nm). With the aid of UV/Vis measurements, the detection limit could be as low as 15 mu M. The probe possessed much higher selectivity for fluoride over other common anions. Excitingly, by virtue of a dipstick approach, F-1 could serve as colorimetric probe for convenient measurements, without the requirement of any additional equipment.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]FLUORESCENT CHEMOSENSOR ; PROTON-TRANSFER ; ANION RECOGNITION ; SODIUM-FLUORIDE ; ION SENSOR ; CELLS ; EFFICIENT ; CHEMODOSIMETER ; COMPLEXATION ; RECEPTOR
收录类别SCI ; IC
语种英语
WOS记录号WOS:000309751300006
公开日期2015-07-14
源URL[http://ir.wipm.ac.cn/handle/112942/1668]  
专题武汉物理与数学研究所_磁共振基础研究部
作者单位1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Xiaohong,Li, Shuang,Xu, Guohua,et al. A Reaction-Based Colorimetric Fluoride Probe: Rapid "Naked-Eye" Detection and Large Absorption Shift[J]. CHEMPLUSCHEM,2012,77(10):908-913.
APA Cheng, Xiaohong,Li, Shuang,Xu, Guohua,Li, Conggang,Qin, Jingui,&Li, Zhen.(2012).A Reaction-Based Colorimetric Fluoride Probe: Rapid "Naked-Eye" Detection and Large Absorption Shift.CHEMPLUSCHEM,77(10),908-913.
MLA Cheng, Xiaohong,et al."A Reaction-Based Colorimetric Fluoride Probe: Rapid "Naked-Eye" Detection and Large Absorption Shift".CHEMPLUSCHEM 77.10(2012):908-913.

入库方式: OAI收割

来源:武汉物理与数学研究所

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