Synthesis of organic-functionalized SAPO-5 with variable content and type of organic Si in the H2O/C2H5OH system
文献类型：期刊论文
| 作者 | Zhou, Dan1; Li, Jiyang2; Chen, Lei3; Liang, Zhiqiang2; Deng, Feng3; Lu, Xinhuan1; Xia, Qinghua1 |
| 刊名 | MATERIALS LETTERS
 |
| 出版日期 | 2013-06-15 |
| 卷号 | 101页码:103-106 |
| 关键词 | Porous materials Spectroscopy Organic-inorganic hybrid molecular sieve Microporous |
| 英文摘要 | Organic-inorganic hybrid microporous molecular sieves have been attracting great attention due to their unique structural features and properties. Herein, in the H2O/C2H5OH system, organic-functionalized SAPO-5 molecular sieves have been firstly synthesized. It is found that the H2O/C2H5OH system is favorable for the hydrolysis of organic silicon source and the synthesis of hybrid molecular sieves, and the content and type of organic silicon (SiC(OH)(2)O-b, SiC(OH)O-2b, SiCO3b, b: bridging oxygen) introduced into inorganic SAPO-5 framework are correlated with the hydrolysis time of organic silicon. When the hydrolysis time of vinyltriethoxysilane is controlled to 12 h, the content of organic Si in the material is the highest. This work proposes a route to synthesize organic-inorganic hybrid microporous SAPOs molecular sieve with high organic group content. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| 类目[WOS] | Materials Science, Multidisciplinary ; Physics, Applied |
| 研究领域[WOS] | Materials Science ; Physics |
| 关键词[WOS] | INORGANIC HYBRID ZEOLITES ; MOLECULAR-SIEVES OFMSS ; FRAMEWORK ; CATALYSTS ; NMR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000320076700029 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/823]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organochem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China 2.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom Mol Physics, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Dan,Li, Jiyang,Chen, Lei,et al. Synthesis of organic-functionalized SAPO-5 with variable content and type of organic Si in the H2O/C2H5OH system[J]. MATERIALS LETTERS,2013,101:103-106. |
| APA | Zhou, Dan.,Li, Jiyang.,Chen, Lei.,Liang, Zhiqiang.,Deng, Feng.,...&Xia, Qinghua.(2013).Synthesis of organic-functionalized SAPO-5 with variable content and type of organic Si in the H2O/C2H5OH system.MATERIALS LETTERS,101,103-106. |
| MLA | Zhou, Dan,et al."Synthesis of organic-functionalized SAPO-5 with variable content and type of organic Si in the H2O/C2H5OH system".MATERIALS LETTERS 101(2013):103-106. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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