中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A high-capacity lithium-air battery with Pd modified carbon nanotube sponge cathode working in regular air

文献类型:期刊论文

作者Shen, Yue1; Sun, Dan1; Yu, Ling1; Zhang, Wang1; Shang, Yuanyuan2; Tang, Huiru3; Wu, Junfang3; Cao, Anyuan2; Huang, Yunhui1
刊名CARBON
出版日期2013-10-01
卷号62页码:288-295
英文摘要We report a lithium-air battery with a free-standing, highly porous Pd-modified carbon nanotube (Pd-CNT) sponge cathode. The Pd-CNT sponge was synthesized through a chemical vapor deposition growth followed with an electrochemical deposition process. To build a whole lithium-air battery, the air cathode is integrated with a ceramic electrolyte-protected lithium metal anode and non-volatile ionic liquid electrolyte. The lithium anode is stable during the operation and long-time storage and the ionic liquid is chemically inert. By controlling the amount of ionic liquid electrolyte, the sponge is wet but not fulfilled by the electrolyte. Such configuration offers a tricontinuous passage for lithium ions, oxygen and electrons, which is propitious to the discharge reaction. In addition, the existence of Pd nanoparticles improves the catalytic reactivity of the oxygen reduction reaction. The battery is durable to any humidity level and delivers a capacity as high as 9092 mA h g(-1). (C) 2013 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Materials Science
关键词[WOS]RECHARGEABLE LI-AIR ; ELECTROCHEMICAL PERFORMANCE ; OXYGEN BATTERY ; LI-O-2 BATTERY ; GLASS-CERAMICS ; SOLID-STATE ; ELECTROLYTE ; GRAPHENE ; ENERGY ; CATALYSTS
收录类别SCI
语种英语
WOS记录号WOS:000322931300032
公开日期2015-07-14
源URL[http://ir.wipm.ac.cn/handle/112942/937]  
专题武汉物理与数学研究所_磁共振应用研究部
作者单位1.Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Hubei, Peoples R China
2.Peking Univ, Dept Mat Sci & Engn, Coll Engn, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
推荐引用方式
GB/T 7714
Shen, Yue,Sun, Dan,Yu, Ling,et al. A high-capacity lithium-air battery with Pd modified carbon nanotube sponge cathode working in regular air[J]. CARBON,2013,62:288-295.
APA Shen, Yue.,Sun, Dan.,Yu, Ling.,Zhang, Wang.,Shang, Yuanyuan.,...&Huang, Yunhui.(2013).A high-capacity lithium-air battery with Pd modified carbon nanotube sponge cathode working in regular air.CARBON,62,288-295.
MLA Shen, Yue,et al."A high-capacity lithium-air battery with Pd modified carbon nanotube sponge cathode working in regular air".CARBON 62(2013):288-295.

入库方式: OAI收割

来源:武汉物理与数学研究所

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