Depolymerization of crystalline cellulose catalyzed by acidic ionic liquids grafted onto sponge-like nanoporous polymers
文献类型：期刊论文
| 作者 | Liu, Fujian1,2; Kamat, Ranjan K.2; Noshadi, Iman2; Peck, Daniel3; Parnas, Richard S.2; Zheng, Anmin4; Qi, Chenze1; Lin, Yao2,3 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2013 |
| 卷号 | 49期号:76页码:8456-8458 |
| 英文摘要 | The acidic ionic liquid (IL) functionalized polymer (PDVB-SO3H-[C(3)vim]-[SO3CF3]) possesses abundant nanoporous structures, strong acid strength and unique capability for deconstruction of crystalline cellulose into sugars in ILs. The polymer shows much improved catalytic activities in comparison with mineral acids, homogeneous acidic ionic liquids and the acidic resins such as Amberlyst 15. The enhanced catalytic activity found in the polymer is attributed to synergistic effects between the strongly acidic group and the ILs grafted onto the polymer, which by itself is capable of breaking down the crystalline structures of cellulose. This study may help develop cost-effective and green routes for conversion of biomass to fuels. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | LIGNOCELLULOSIC BIOMASS ; SOLID ACID ; HYDROLYSIS ; TRANSFORMATION ; CHEMICALS ; BIOFUELS ; FUELS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323726600008 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/939]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Shaoxing Univ, Dept Chem, Key Lab Alternat Technol Fine Chem Proc Zhejiang, Shaoxing 312000, Peoples R China 2.Univ Connecticut, Inst Mat Sci, Polymer Program, Storrs, CT 06269 USA 3.Univ Connecticut, Dept Chem, Storrs, CT 06269 USA 4.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Fujian,Kamat, Ranjan K.,Noshadi, Iman,et al. Depolymerization of crystalline cellulose catalyzed by acidic ionic liquids grafted onto sponge-like nanoporous polymers[J]. CHEMICAL COMMUNICATIONS,2013,49(76):8456-8458. |
| APA | Liu, Fujian.,Kamat, Ranjan K..,Noshadi, Iman.,Peck, Daniel.,Parnas, Richard S..,...&Lin, Yao.(2013).Depolymerization of crystalline cellulose catalyzed by acidic ionic liquids grafted onto sponge-like nanoporous polymers.CHEMICAL COMMUNICATIONS,49(76),8456-8458. |
| MLA | Liu, Fujian,et al."Depolymerization of crystalline cellulose catalyzed by acidic ionic liquids grafted onto sponge-like nanoporous polymers".CHEMICAL COMMUNICATIONS 49.76(2013):8456-8458. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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