Design and synthesis of hydrophobic and stable mesoporous polymeric solid acid with ultra strong acid strength and excellent catalytic activities for biomass transformation
文献类型：期刊论文
| 作者 | Liu, Fujian1,3; Zheng, Anmin2; Noshadi, Iman4; Xiao, Feng-Shou3 |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2013-06-05 |
| 卷号 | 136页码:193-201 |
| 关键词 | Solid strong acid Mesoporous polymers Hydrophobicity Wettability Biomass transformation |
| 英文摘要 | Novel and efficient mesoporous polydivinylbenzene (PDVB) based solid strong acid (PDVB-SO3H-SO2CF3) has been successfully prepared by grafting of strong electron withdrawing group of -SO2CF3 onto the network of performed mesoporous solid acid of PDVB-SO3H, which could be synthesized from sulfonation of superhydrophobic mesoporous PDVB or copolymerization of DVB with sodium p-styrene sulfonate. Characterizations of N-2 sorption isotherms, TG curves and contact angle tests show that PDVB-SO3H-SO2CF3 has large Brunauer-Emmett-Teller (BET) surface area, superior thermal stability, good hydrophobicity and oleophilicity. Solid P-31 NMR spectra and NH3-TPD curves show that the Bronsted acidic site in PDVB-SO3H-SO2CF3 has been significantly enhanced and rather homogeneously distributed when compared with that of PDVB-SO3H. Catalytic tests show that PDVB-SO3H-SO2CF3 exhibits excellent catalytic activities and good recyclability in biomass transformation toward transesterification to biodiesel and depolymerization of crystalline cellulose to sugars when compared with those of PDVB-SO3 H, solid strong acids of SO4/ZrO2 and Nafion NR50. The excellent catalytic activity and good recyclability of PDVB-SO3H-SO2CF3 result from its unique characters such as large surface area, ultra strong acid strength, adjustable hydrophobic-oleophilic and stable network. (C) 2013 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Engineering, Environmental ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | NAFION RESIN/SILICA NANOCOMPOSITES ; SULFATED ZIRCONIA ; IONIC LIQUIDS ; HETEROGENEOUS CATALYSIS ; BIODIESEL PRODUCTION ; METAL-OXIDES ; P-31 NMR ; HYDROLYSIS ; SILICA ; ESTERIFICATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317539400023 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/953]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Zhejiang, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China 3.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China 4.Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA |
| 推荐引用方式 GB/T 7714 | Liu, Fujian,Zheng, Anmin,Noshadi, Iman,et al. Design and synthesis of hydrophobic and stable mesoporous polymeric solid acid with ultra strong acid strength and excellent catalytic activities for biomass transformation[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2013,136:193-201. |
| APA | Liu, Fujian,Zheng, Anmin,Noshadi, Iman,&Xiao, Feng-Shou.(2013).Design and synthesis of hydrophobic and stable mesoporous polymeric solid acid with ultra strong acid strength and excellent catalytic activities for biomass transformation.APPLIED CATALYSIS B-ENVIRONMENTAL,136,193-201. |
| MLA | Liu, Fujian,et al."Design and synthesis of hydrophobic and stable mesoporous polymeric solid acid with ultra strong acid strength and excellent catalytic activities for biomass transformation".APPLIED CATALYSIS B-ENVIRONMENTAL 136(2013):193-201. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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