Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicate
文献类型：期刊论文
| 作者 | Fang, Xiangqing1; Wang, Qiang2; Zheng, Anmin2; Liu, Yueming1; Lin, Longfei1; Wu, Haihong1; Deng, Feng2; He, Mingyuan1; Wu, Peng1 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:14页码:4930-4938 |
| 英文摘要 | F-Ti-MWW was post-synthesized by implanting fluorine species into a Ti-MWW framework through an acid treatment process in the presence of ammonium fluoride. The effects of NH4F addition amount, acid treatment temperature and precursor Ti content were investigated on the incorporation of F species, the zeolite structure and the coordination sites of Ti. Fluorine-implanting improved the surface hydrophobicity of the zeolite and altered the electropositivity nearby the tetrahedral Ti sites through forming the SiO3/2F and SiO4/2F- units. The negative effect of SiO4/2F- units in F-Ti-MWW was eliminated selectively by convenient anion-exchange with various alkali chlorides. F-Ti-MWW containing the SiO3/2F units possessed better catalytic activity and reusability, and a longer catalyst lifetime than conventional Ti-MWW. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 研究领域[WOS] | Chemistry ; Physics |
| 关键词[WOS] | HYDROGEN-PEROXIDE ; TI-MWW ; HYDROTHERMAL SYNTHESIS ; SELECTIVE PRODUCTION ; ALKENE EPOXIDATION ; TITANIUM SILICATES ; HIGHLY EFFICIENT ; MOLECULAR-SIEVES ; ALLYL CHLORIDE ; ACTIVE-SITES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000316007900011 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/957]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Xiangqing,Wang, Qiang,Zheng, Anmin,et al. Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicate[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2013,15(14):4930-4938. |
| APA | Fang, Xiangqing.,Wang, Qiang.,Zheng, Anmin.,Liu, Yueming.,Lin, Longfei.,...&Wu, Peng.(2013).Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicate.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,15(14),4930-4938. |
| MLA | Fang, Xiangqing,et al."Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicate".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 15.14(2013):4930-4938. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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