Progress in development and application of solid-state NMR for solid acid catalysis
文献类型：期刊论文
| 作者 | Zheng Anmin1; Huang Shing-Jong2; Wang Qiang1; Zhang Hailu3; Deng Feng1; Liu Shang-Bin4,5 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2013-03-01 |
| 卷号 | 34期号:3页码:436-491 |
| 关键词 | Solid-state NMR spectroscopy Solid acid catalyst Probe molecule Acidity Catalytic reaction mechanism |
| 英文摘要 | Solid acid catalysts have been widely used in petrochemical industry and their catalytic activities are normally dictated by their acidities. Unlike conventional acidity characterization techniques such as titration, infrared, or temperature-programmed desorption, detailed acid features of solid acids, such as type, distribution, concentration, and strength of acid sites may be attained by advanced methods involving pertinent probe molecules and state-of-the-art solid-state nuclear magnetic resonance (SSNMR) techniques, i.e. double resonance and two-dimensional correlation spectroscopies. In addition, in situ solid-state NMR method is capable of probing the guest/host properties of the reactant at the active centers of the catalysts as well as the intermediate species formed during conversion. It provides direct experimental evidence for exploring the mechanism of catalytic reaction. In this report, the fundamental theory and the recent developments in solid-state NMR are reviewed with specific focus on relevant applications in structure and acidity characterization of solid acid catalysts and catalytic mechanisms. (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Engineering |
| 关键词[WOS] | NUCLEAR-MAGNETIC-RESONANCE ; ANGLE-SPINNING NMR ; IN-SITU NMR ; PROBE MOLECULE TRIMETHYLPHOSPHINE ; INTEGER QUADRUPOLAR NUCLEI ; C-13 CHEMICAL-SHIFT ; H-1/AL-27 TRAPDOR NMR ; MULTIPLE-PULSE NMR ; MAGIC-ANGLE ; ZEOLITE HY |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317873600003 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1032]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan Ctr Magnet Resonance, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 2.Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Jiangsu, Peoples R China 4.Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan 5.Natl Taiwan Normal Univ, Dept Chem, Taipei 11677, Taiwan |
| 推荐引用方式 GB/T 7714 | Zheng Anmin,Huang Shing-Jong,Wang Qiang,et al. Progress in development and application of solid-state NMR for solid acid catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2013,34(3):436-491. |
| APA | Zheng Anmin,Huang Shing-Jong,Wang Qiang,Zhang Hailu,Deng Feng,&Liu Shang-Bin.(2013).Progress in development and application of solid-state NMR for solid acid catalysis.CHINESE JOURNAL OF CATALYSIS,34(3),436-491. |
| MLA | Zheng Anmin,et al."Progress in development and application of solid-state NMR for solid acid catalysis".CHINESE JOURNAL OF CATALYSIS 34.3(2013):436-491. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。