Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions
文献类型：期刊论文
| 作者 | Wang, Wenlong1,2; Zheng, Anmin3; Zhao, Peiqing1; Xia, Chungu1; Li, Fuwei1,4 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2014 |
| 卷号 | 4期号:1页码:321-327 |
| 关键词 | N-heterocyclic carbene porous organic polymers synthetic control alkyne hydration cross-coupling |
| 英文摘要 | The synthetic control and functions of porous organic polymers (POPs) with N-heterocyclic carbene gold(I) (Au-NHC@POPs) are described in this article. A series of Au-NHC@POPs with tunable physical properties such as surface area and pore size distribution were first synthesized via Sonogashira chemistry by differing monomer strut lengths and concentration during polymerization; a controllable transition from nonporous to microporous and the coexistence of micro- and mesoporous structures in the framework were realized by varying the monomer concentration. To explain this phenomenon, we put forward a model assumption of a branch-branch cross effect. Additionally, Au-NHC@POPs1 was found to have superior catalytic activity in alkyne hydration reactions, and the catalyst could be used six times with a slight loss of activity. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | N-HETEROCYCLIC CARBENE ; CONJUGATED MICROPOROUS POLYMERS ; OLEFIN METATHESIS CATALYSTS ; MIYAURA COUPLING REACTION ; HIGH-SURFACE-AREA ; HETEROGENEOUS CATALYSIS ; HOMOGENEOUS CATALYSIS ; METAL-COMPLEXES ; FRAMEWORKS ; NETWORKS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000329472600038 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1288]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Chinese Acad Sci, Wuhan Ctr Magnet Resonance, Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Suzhou Inst Nanotech & NanoBion, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wenlong,Zheng, Anmin,Zhao, Peiqing,et al. Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions[J]. ACS CATALYSIS,2014,4(1):321-327. |
| APA | Wang, Wenlong,Zheng, Anmin,Zhao, Peiqing,Xia, Chungu,&Li, Fuwei.(2014).Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions.ACS CATALYSIS,4(1),321-327. |
| MLA | Wang, Wenlong,et al."Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions".ACS CATALYSIS 4.1(2014):321-327. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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