Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties
文献类型：期刊论文
| 作者 | Liu, Bing1; Ben, Teng2; Xu, Jun3; Deng, Feng3; Qiu, Shilun1 |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2014-06-01 |
| 卷号 | 38期号:6页码:2292-2299 |
| 英文摘要 | A microporous organic framework (JUC-Z12) was synthesized quantitatively from tetra(4-formylphenyl)methane and 3,3'-diaminobenzidine. JUC-Z12 shows high thermal stability (>400 degrees C), a large surface area (S-BET = 750 m(2) g(-1)), a well-defined uniform micropore distribution (1.09 nm) and high Q(st) for H-2 (-8.1 kJ mol(-1)), CO2 (-29.5 kJ mol(-1)), and CH4 (-22.2 kJ mol(-1)). It also exhibits selective catalytic activities in the Knoevenagel reaction, which is supposed to be controlled by hydrogen bonding between substrates and JUC-Z12. The JUC-Z12 catalyst can be easily isolated from the reaction mixture by simple filtration and reused with high activity. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HIGH-SURFACE-AREA ; CONJUGATED MICROPOROUS POLYMERS ; KNOEVENAGEL CONDENSATION ; HETEROGENEOUS CATALYST ; CO2 UPTAKE ; LINKED POLYMERS ; METHANE STORAGE ; CARBON-DIOXIDE ; AQUEOUS-MEDIUM ; NETWORKS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336821000018 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1359]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Jilin Univ, Dept Chem, Changchun 130012, Peoples R China 3.Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Bing,Ben, Teng,Xu, Jun,et al. Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties[J]. NEW JOURNAL OF CHEMISTRY,2014,38(6):2292-2299. |
| APA | Liu, Bing,Ben, Teng,Xu, Jun,Deng, Feng,&Qiu, Shilun.(2014).Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties.NEW JOURNAL OF CHEMISTRY,38(6),2292-2299. |
| MLA | Liu, Bing,et al."Hydrogen bonding controlled catalysis of a porous organic framework containing benzimidazole moieties".NEW JOURNAL OF CHEMISTRY 38.6(2014):2292-2299. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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