Highly sensitive detection of mercury (II) in aqueous media by tetraphenylporphyrin with a metal ion receptor
文献类型：期刊论文
| 作者 | Guo, Qianni; Zeng, Qingbin; Zhang, Xiaoxiao; Zhou, Xin |
| 刊名 | SUPRAMOLECULAR CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 26期号:10-12页码:836-842 |
| 关键词 | porphyrin chemosensor mercury relaxivity |
| 英文摘要 | We provide a highly sensitive and selective assay to detect Hg2+ in aqueous solutions using a novel beta-functionalised porphyrin-based chemosensor 5 at room temperature. The binding properties of the chemosensor 5 for cations were examined by UV-vis spectroscopy and H-1 NMR. The results indicate that a 1: 1 stoichiometric complex is formed between chemosensor 5 and mercury (II) ion. The recognition mechanism between chemosensor 5 and metal ion was discussed based on their absorbance changes and the chemical shift changes when they interact with each other. Control experiments revealed that chemosensor 5 has a selective response to mercury (II) ion compared with other metal ions. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FLUORESCENT SENSOR ; SELECTIVE DETECTION ; ENERGY-TRANSFER ; CHEMOSENSOR ; PORPHYRINS ; MODULATION ; RESONANCE ; DESIGN ; CARBON ; CELLS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000342284600017 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1398]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | Chinese Acad Sci, Key Lab Magnet Resonance Biol Syst, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance,Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Qianni,Zeng, Qingbin,Zhang, Xiaoxiao,et al. Highly sensitive detection of mercury (II) in aqueous media by tetraphenylporphyrin with a metal ion receptor[J]. SUPRAMOLECULAR CHEMISTRY,2014,26(10-12):836-842. |
| APA | Guo, Qianni,Zeng, Qingbin,Zhang, Xiaoxiao,&Zhou, Xin.(2014).Highly sensitive detection of mercury (II) in aqueous media by tetraphenylporphyrin with a metal ion receptor.SUPRAMOLECULAR CHEMISTRY,26(10-12),836-842. |
| MLA | Guo, Qianni,et al."Highly sensitive detection of mercury (II) in aqueous media by tetraphenylporphyrin with a metal ion receptor".SUPRAMOLECULAR CHEMISTRY 26.10-12(2014):836-842. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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