Selective Catalytic Production of 5-Hydroxymethylfurfural from Glucose by Adjusting Catalyst Wettability
文献类型：期刊论文
| 作者 | Wang, Liang1; Wang, Hong2; Liu, Fujian1; Zheng, Anmin3; Zhang, Jian1; Sun, Qi1; Lewis, James P.2; Zhu, Longfeng4; Meng, Xiangju1; Xiao, Feng-Shou1 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 7期号:2页码:402-406 |
| 关键词 | 5-hydroxymethylfurfural biomass fructose glucose superhydrophilic base |
| 英文摘要 | The development of highly-efficient catalysts for conversion of glucose and fructose to 5-hydroxymethylfurfural (HMF) is of great importance. In this work, theoretical simulations form the basis for rational design and synthesis of a superhydrophobic mesoporous acid, that can completely prevent HMF hydration, giving HMF as sole product from full conversion of fructose. Interestingly, the combined superhydrophobic solid acid and superhydrophilic solid base catalysts are very efficient for one-pot conversion of glucose to HMF, giving a yield as high as 95.4 %. The excellent catalytic data in the conversion of glucose to HMF is attributed to the unique wettabilities of the solid acid and base catalysts. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SOLID ACID CATALYSTS ; HETEROGENEOUS CATALYSTS ; LIGNOCELLULOSIC BIOMASS ; GAMMA-VALEROLACTONE ; SUGAR CONVERSION ; IONIC LIQUIDS ; LACTIC-ACID ; DEHYDRATION ; FRUCTOSE ; TRANSFORMATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000336804000006 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1408]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China 2.W Virginia Univ, Dept Phys, Morgantown, WV 26506 USA 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 4.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Liang,Wang, Hong,Liu, Fujian,et al. Selective Catalytic Production of 5-Hydroxymethylfurfural from Glucose by Adjusting Catalyst Wettability[J]. CHEMSUSCHEM,2014,7(2):402-406. |
| APA | Wang, Liang.,Wang, Hong.,Liu, Fujian.,Zheng, Anmin.,Zhang, Jian.,...&Xiao, Feng-Shou.(2014).Selective Catalytic Production of 5-Hydroxymethylfurfural from Glucose by Adjusting Catalyst Wettability.CHEMSUSCHEM,7(2),402-406. |
| MLA | Wang, Liang,et al."Selective Catalytic Production of 5-Hydroxymethylfurfural from Glucose by Adjusting Catalyst Wettability".CHEMSUSCHEM 7.2(2014):402-406. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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