Formation of Subnanometer Zr-WOx Clusters within Mesoporous W-Zr Mixed Oxides as Strong Solid Acid Catalysts for Friedel-Crafts Alkylation
文献类型：期刊论文
| 作者 | Li, Sha1; Zhou, Hui1; Jin, Chuanhong2; Feng, Ningdong3; Liu, Fen3; Deng, Feng3; Wang, Jian-Qiang4; Huang, Wei2; Xiao, Liping1; Fan, Jie1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2014-03-27 |
| 卷号 | 118期号:12页码:6283-6290 |
| 英文摘要 | WO3-ZrO2 mixed metal oxides is an important class of acid solid. Here, we successfully synthesized a variety of mesoporous WO3-ZrO2 mixed metal oxides by a well-controlled sol-gel process (AcHE) using Zr(OBu)(4) and WCl6 as the inorganic precursors in the presence of poly block copolymer F127. Their structures and acid properties have been well characterized by XRD, Raman, N-2 adsorption measurement, and HRTEM analyses. In addition, new insights from TG-DSC and P-31 NMR characterization also provide useful information on the formation of strong acidity of this important solid acid. Moreover, their structure-to-properties relationship has been studied in the Friedel-Crafts (F-C) reaction of anisole and benzyl alcohol. We identified that the subnanometer WOx clusters act as the most active sites for the F-C reaction. Most importantly, we show that the formation of these subnanometer WOx clusters can be rationally controlled. It is shown that a minimum W concentration (0.07 at the calcination temperature of 800 degrees C) and a minimum calcination temperature (650 degrees C at a given W concentration of 0.1) are required during the preparation of these acid catalysts for the development of highly active subnano WOx clusters. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | TUNGSTEN-OXIDE ; PHOTOELECTRON-SPECTROSCOPY ; STRUCTURAL-ANALYSIS ; P-31 NMR ; N-BUTANE ; ZIRCONIA ; ISOMERIZATION ; WO3/ZRO2 ; SITES ; WOX/ZRO2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000333578300034 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1490]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China 2.Zhejiang Univ, Dept Mat Sci & Engn, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei Province, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Sha,Zhou, Hui,Jin, Chuanhong,et al. Formation of Subnanometer Zr-WOx Clusters within Mesoporous W-Zr Mixed Oxides as Strong Solid Acid Catalysts for Friedel-Crafts Alkylation[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2014,118(12):6283-6290. |
| APA | Li, Sha.,Zhou, Hui.,Jin, Chuanhong.,Feng, Ningdong.,Liu, Fen.,...&Fan, Jie.(2014).Formation of Subnanometer Zr-WOx Clusters within Mesoporous W-Zr Mixed Oxides as Strong Solid Acid Catalysts for Friedel-Crafts Alkylation.JOURNAL OF PHYSICAL CHEMISTRY C,118(12),6283-6290. |
| MLA | Li, Sha,et al."Formation of Subnanometer Zr-WOx Clusters within Mesoporous W-Zr Mixed Oxides as Strong Solid Acid Catalysts for Friedel-Crafts Alkylation".JOURNAL OF PHYSICAL CHEMISTRY C 118.12(2014):6283-6290. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。