Preparation of Mesoporous Zeolite ETS-10 Catalysts for High-Yield Synthesis of alpha, beta-Epoxy Ketones
文献类型：期刊论文
| 作者 | Xiang, Mei1; Ni, Xiaojun1; Yi, Xianfeng2; Zheng, Anmin2; Wang, Wenchang3; He, Mingyang3; Xiong, Jing1; Liu, Taotao1; Ma, Yuli1; Zhu, Pengyuan1 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 7期号:3页码:521-525 |
| 关键词 | aldehydes epoxidation mesoporous materials ketones zeolites |
| 英文摘要 | Developing highly active heterogeneous catalysts for the efficient construction of valuable building blocks is of great importance to synthetic chemistry. For this purpose, a mesoporous zeolite ETS-10 (METS-10) is synthesized by using a mesoscale silane surfactant as a template and applied to achieve highly efficient syntheses of ,-epoxy ketones by employing simple alkenes and aldehydes as starting materials. The high activity of the METS-10 catalyst is attributed to its unique porous structure and basicity. Electron paramagnetic resonance characterization results and theoretical calculation experimental data reveal that the strong basic sites on METS-10 catalyst can activate the reaction substrate and intermediate. In addition, the mesopores in METS-10 catalyst benefit the mass transfer and further improve the catalytic activity. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | MICROPOROUS TITANOSILICATE ETS-10 ; ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; CHIRAL ALPHA,BETA-EPOXY KETONES ; TERT-BUTYL HYDROPEROXIDE ; ASYMMETRIC EPOXIDATION ; HYDROGEN-PEROXIDE ; ALDEHYDES ; CHEMISTRY ; RADICALS ; ACETANILIDES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349147100021 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1515]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou City 325035, Zhejiang, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.Changzhou Univ, Coll Chem & Chem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiang, Mei,Ni, Xiaojun,Yi, Xianfeng,et al. Preparation of Mesoporous Zeolite ETS-10 Catalysts for High-Yield Synthesis of alpha, beta-Epoxy Ketones[J]. CHEMCATCHEM,2015,7(3):521-525. |
| APA | Xiang, Mei.,Ni, Xiaojun.,Yi, Xianfeng.,Zheng, Anmin.,Wang, Wenchang.,...&Tang, Tiandi.(2015).Preparation of Mesoporous Zeolite ETS-10 Catalysts for High-Yield Synthesis of alpha, beta-Epoxy Ketones.CHEMCATCHEM,7(3),521-525. |
| MLA | Xiang, Mei,et al."Preparation of Mesoporous Zeolite ETS-10 Catalysts for High-Yield Synthesis of alpha, beta-Epoxy Ketones".CHEMCATCHEM 7.3(2015):521-525. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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