Molecular engineering of microporous crystals: (V) Investigation of the structure-directing ability of piperazine in forming two layered aluminophosphates
文献类型：期刊论文
| 作者 | Tong, Xiaoqiang1; Xu, Jun2; Wang, Chao2; Lu, Huiying1; Huang, Pai1; Yan, Wenfu1; Yu, Jihong1; Deng, Feng2; Xu, Ruren1 |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2012-06-01 |
| 卷号 | 155页码:153-166 |
| 关键词 | Zeolite Aluminophosphate Templating effect Structure-directing role Piperazine |
| 英文摘要 | The crystallization process of the layered aluminophosphates AP2pip and AIPO-CJ9 from initial mixtures with compositions of Al2O3:P2O3:1.1 piperazine:277 H2O and Al2O3:P2O3:4.0 piperazine:277 H2O, respectively, was investigated using multiple techniques. During the crystallization of AP2pip, the formation and dissolution of highly polymerized but structurally disordered fragments containing four-coordinated P sites to Al-centered polyhedra were observed. Al-27 -> P-31 CP/MAS HETCOR NMR analysis showed that the local P-site environment in the small building fragments formed in the initial mixture is same as that in the final crystal structure of AP2pip. The concentration of these small building fragments is very low. During the crystallization of AIPO-CJ9, the formation of small building fragments with the local P-site environment same or very similar to that observed in the final structure of AIPO-CJ9 were observed. The concentration of these small building fragments is high. These small fragments contained at least two complete coordination layers. The difference in the structure-directing role played by piperazine in the two synthesis systems was investigated in detail by designing several control experiments and analyzing the arrangements of the piperazine molecules in the interlayer region of AP2pip and AIPO-CJ9. (C) 2012 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | SILICALITE-1 CRYSTALLIZATION ; GUEST/HOST RELATIONSHIPS ; FRAMEWORK TOPOLOGY ; RATIONAL SYNTHESIS ; ORGANIC-MOLECULES ; INORGANIC SOLIDS ; SIEVE SYNTHESIS ; ZEOLITE-A ; UV-RAMAN ; NMR |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000302893400021 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1621]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Xiaoqiang,Xu, Jun,Wang, Chao,et al. Molecular engineering of microporous crystals: (V) Investigation of the structure-directing ability of piperazine in forming two layered aluminophosphates[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2012,155:153-166. |
| APA | Tong, Xiaoqiang.,Xu, Jun.,Wang, Chao.,Lu, Huiying.,Huang, Pai.,...&Xu, Ruren.(2012).Molecular engineering of microporous crystals: (V) Investigation of the structure-directing ability of piperazine in forming two layered aluminophosphates.MICROPOROUS AND MESOPOROUS MATERIALS,155,153-166. |
| MLA | Tong, Xiaoqiang,et al."Molecular engineering of microporous crystals: (V) Investigation of the structure-directing ability of piperazine in forming two layered aluminophosphates".MICROPOROUS AND MESOPOROUS MATERIALS 155(2012):153-166. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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