Molecular engineering of microporous crystals: (VI) Structure-directing effect in the crystallization process of layered aluminophosphates
文献类型：期刊论文
| 作者 | Tong, Xiaoqiang1; Xu, Jun2; Xin, Liang1,3; Huang, Pai1; Lu, Huiying1; Wang, Chao2; Yan, Wenfu1; Yu, Jihong1; Deng, Feng2; Sun, Huai3 |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 164页码:56-66 |
| 关键词 | Layered aluminophosphate Piperazine Structure-directing effect Template effect Zeolite |
| 英文摘要 | The products of piperazine-directed synthesis of two-dimensional (20) aluminophosphates, AP2pip and AIPO-CJ9, that were crystallized under different conditions for different periods of time were freeze-dried and characterized using XRD and NMR techniques. The core units of the layered aluminophosphates including AP2pip, AIPO-CJ9, and L-DAP, which was hydrothermally synthesized in the presence of racemic 1,2-diaminopropane, were obtained by applying a "reverse evolution" process to their structures. The factors affecting the structure-directing ability of piperazine under acidic and basic conditions were analyzed. The cooperative role of water in directing the layered aluminophosphate of AP2pip under acidic conditions is discussed. After a thorough analysis of the core units of AIPO-CJ9 and L-DAP, a new phenomenon of a "topological-structure-directing effect" or a "topological-templating effect" was observed. The observation of the new phenomenon of a topological-structure-directing effect or a topological-templating effect may contribute to a deeper understanding of the nature or origin of the "structure-directing or templating effect". (C) 2012 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | DRY-GEL CONVERSION ; SOLID-STATE NMR ; FRAMEWORK ALUMINOPHOSPHATE ; HYDROTHERMAL CONDITIONS ; PIPERAZINE ; MECHANISM ; SIEVE ; SPECTROSCOPY ; PHOSPHATES ; ALPO4-11 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000310770100009 |
| 公开日期 | 2015-07-14 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/1644]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 3.Shanghai Jiao Tong Univ, Coll Chem & Chem Engn, Shanghai 200240, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Xiaoqiang,Xu, Jun,Xin, Liang,et al. Molecular engineering of microporous crystals: (VI) Structure-directing effect in the crystallization process of layered aluminophosphates[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2012,164:56-66. |
| APA | Tong, Xiaoqiang.,Xu, Jun.,Xin, Liang.,Huang, Pai.,Lu, Huiying.,...&Xu, Ruren.(2012).Molecular engineering of microporous crystals: (VI) Structure-directing effect in the crystallization process of layered aluminophosphates.MICROPOROUS AND MESOPOROUS MATERIALS,164,56-66. |
| MLA | Tong, Xiaoqiang,et al."Molecular engineering of microporous crystals: (VI) Structure-directing effect in the crystallization process of layered aluminophosphates".MICROPOROUS AND MESOPOROUS MATERIALS 164(2012):56-66. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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