An experimental and quantum mechanical study on luminescence properties of SM(beta-Nbm)(3)center dot(Pd)
文献类型:期刊论文
作者 | Li, Yueqin1; Li, Ye1; Chu, Yueying2; Tao, Xian1; Xu, Huihua1; Shen, Yingzhong1; Zheng, Anmin2 |
刊名 | JOURNAL OF LUMINESCENCE
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出版日期 | 2012-07-01 |
卷号 | 132期号:7页码:1663-1667 |
关键词 | Samarium complex Photoluminescence OLEDs Energy levels |
英文摘要 | A new ternary samarium complex Sm(beta-NBM)(3)center dot(PD) has been synthesized by the reaction of SmCl3 center dot 6H(2)O with beta-naphthoylbenzoylmethane (beta-HNBM) and 1,10-phenanthroline-5,6-dione (PD) in stoichiometry. The new samarium complex obtained was characterized by elemental analysis, H-1 NMR, and FT-IR spectroscopy. The absorption and emission of this complex were systematically investigated. Photoluminescence studies indicated that the energy absorbed by the organic ligands was efficiently transferred to the central Sm3+ ions and the complex showed intensely and characteristically orange emission due to the (4)G(5/2) -> H-6(j) transitions of the central Sm3+ ions. The energy levels (HOMO and LUMO) of the ligands and the complex were further confirmed by computer simulation and cyclic voltammetry, respectively. All the results suggested that the synthesized Sm(beta-NBM)(3)center dot(PD) would have the potential application for organic light-emitting diodes. (C) 2012 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Optics |
研究领域[WOS] | Optics |
关键词[WOS] | ORGANIC ELECTROLUMINESCENT DEVICES ; LIGHT-EMITTING DEVICES ; SAMARIUM COMPLEX ; EUROPIUM COMPLEX ; UNITS ; PERFORMANCE ; DERIVATIVES ; EFFICIENCY ; HOST |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000303297200010 |
公开日期 | 2015-07-14 |
源URL | [http://ir.wipm.ac.cn/handle/112942/1739] ![]() |
专题 | 武汉物理与数学研究所_磁共振应用研究部 |
作者单位 | 1.Nanjing Univ Aeronaut & Astronaut, Sch Mat Sci & Engn, Dept Appl Chem, Nanjing 210016, Jiangsu, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Yueqin,Li, Ye,Chu, Yueying,et al. An experimental and quantum mechanical study on luminescence properties of SM(beta-Nbm)(3)center dot(Pd)[J]. JOURNAL OF LUMINESCENCE,2012,132(7):1663-1667. |
APA | Li, Yueqin.,Li, Ye.,Chu, Yueying.,Tao, Xian.,Xu, Huihua.,...&Zheng, Anmin.(2012).An experimental and quantum mechanical study on luminescence properties of SM(beta-Nbm)(3)center dot(Pd).JOURNAL OF LUMINESCENCE,132(7),1663-1667. |
MLA | Li, Yueqin,et al."An experimental and quantum mechanical study on luminescence properties of SM(beta-Nbm)(3)center dot(Pd)".JOURNAL OF LUMINESCENCE 132.7(2012):1663-1667. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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