NMR DETERMINATION OF SPATIAL STRUCTURE OF SMALL MOLECULES IN SOLUTION
文献类型：期刊论文
| 作者 | Wu Donghui; Shen Lianfang |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1992 |
| 卷号 | 8期号:1页码:39-44 |
| 关键词 | Three dimensional configuration NMR relaxation matrix analysis molecular mechanics calculation TRANILAST |
| 英文摘要 | In this paper,the full relaxation matrix analysis method was applied for processing the peak intensity matrix of the phase sensitive NOESY spectrum for which a relatively long mixing time was used for the small molecules in the "extreme narrowing" condition. According to this method, the cross relaxation rates between nuclei were obtained by diagonalizing the 2D peak intensity matrix,then the inter-nuclear distances were calculated according to R-ij infinity tau(o).r(ij)(-6). This method was employed to investigate the structure of TRANILAST in acetone solution, and the results agree with the data from molecular mechanics calculation. Thus the molecular structure was determined and it was found that there is an internal hydrogen bond in the molecule. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207574100009 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4374]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | Chinese Acad Sci, Wuhan Inst Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu Donghui,Shen Lianfang. NMR DETERMINATION OF SPATIAL STRUCTURE OF SMALL MOLECULES IN SOLUTION[J]. ACTA PHYSICO-CHIMICA SINICA,1992,8(1):39-44. |
| APA | Wu Donghui,&Shen Lianfang.(1992).NMR DETERMINATION OF SPATIAL STRUCTURE OF SMALL MOLECULES IN SOLUTION.ACTA PHYSICO-CHIMICA SINICA,8(1),39-44. |
| MLA | Wu Donghui,et al."NMR DETERMINATION OF SPATIAL STRUCTURE OF SMALL MOLECULES IN SOLUTION".ACTA PHYSICO-CHIMICA SINICA 8.1(1992):39-44. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。