One-pot synthesis of mesoporous organosilicas using sodium silicate as a substitute for tetraalkoxysilane
文献类型：期刊论文
| 作者 | Yu, NY; Gong, YJ; Wu, D; Sun, YH; Luo, Q; Liu, WY; Deng, F |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2004-07-08 |
| 卷号 | 72期号:1-3页码:25-32 |
| 关键词 | MSU-type mesoporous organosilica sodium silicate TEOS organotrialkoxysilane |
| 英文摘要 | Organic-inorganic hybrid mesoporous silicas of MSU with different sizes of organic functionalities of methyl, vinyl, or 3-mercaptopropyl were prepared by using inexpensive sodium silicate and organotrialkoxysilane as the silica precursor via fluoride-mediated co-condensation. The results indicated that both sodium silicate and organotrialkoxysilane could be translated quantitatively into organic-inorganic hybrid materials with high BET surface area (899-1042 m(2)/g) and pore volume (0.70-1.09 cm(3)/g). The key to the synthesis of such materials from sodium silicate-organotrialkoxysilane was the separation of hydrolysis and condensation of silica precursor to avoid phase separation due to the obvious difference of condensation rate between aqueous silicate (solution of sodium silicate) and organotrialkoxysilane. Compared with the materials prepared from tetraethoxysilane (TEOS)-organotrialkoxysilane under the same synthetic conditions, the derivatives from sodium silicate-organotrialkoxysilane owned more ordered framework structure and narrower pore diameter distribution due to faster condensation of aqueous silicate. (C) 2004 Elsevier Inc. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | MSU-X SILICA ; ONE-STEP SYNTHESIS ; MOLECULAR-SIEVES ; SURFACTANT ; FUNCTIONALITY ; ADSORBENTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000222570400002 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4439]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Inst Phys & Math, State Key Lab Magnet Resonance & Atom Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, NY,Gong, YJ,Wu, D,et al. One-pot synthesis of mesoporous organosilicas using sodium silicate as a substitute for tetraalkoxysilane[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2004,72(1-3):25-32. |
| APA | Yu, NY.,Gong, YJ.,Wu, D.,Sun, YH.,Luo, Q.,...&Deng, F.(2004).One-pot synthesis of mesoporous organosilicas using sodium silicate as a substitute for tetraalkoxysilane.MICROPOROUS AND MESOPOROUS MATERIALS,72(1-3),25-32. |
| MLA | Yu, NY,et al."One-pot synthesis of mesoporous organosilicas using sodium silicate as a substitute for tetraalkoxysilane".MICROPOROUS AND MESOPOROUS MATERIALS 72.1-3(2004):25-32. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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