Ultraviolet photodissociation of 1-bromopropane at 234 and 267 nm
文献类型:期刊论文
作者 | Zhang, S; Wang, YM; Tang, BF; Zheng, QS; Zhang, B |
刊名 | CHEMICAL PHYSICS LETTERS |
出版日期 | 2005-09-15 |
卷号 | 413期号:1-3页码:129-134 |
英文摘要 | The photodissociation of 1-bromopropane was investigated at 234 and 267 nm utilizing ion velocity imaging method. Both the speed and angular distributions of Br*((2)p(1/2)) and Br(P-2(3/2)) fragments were determined. ss(Br)= 0.77 +/- 0.07 and ss(Br*)= 1.68 +/- 0.06 at 234 nm; ss(Br)= 0.38 +/- 0.02 and ss(Br*)= 1.33 +/- 0.09 at 267 nm were observed. The total translational energy distributions were single Gaussian distribution and interpreted using soft or rigid implusive mode at different wavelength, respectively. The experiment also shows that Br is dominant in the dissociation and originates mostly from W, while Br* corresponds to 4A' <- 3A' coupling. (c) 2005 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
研究领域[WOS] | Chemistry ; Physics |
关键词[WOS] | TRIATOMIC PHOTOFRAGMENT SPECTRA ; NO2 PHOTODISSOCIATION ; MOLECULAR-OXYGEN ; A-BAND ; DYNAMICS ; BROMIDE ; PHOTOELECTRON ; CH2BRCL ; CH3BR |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000231929400024 |
公开日期 | 2015-07-28 |
源URL | [http://ir.wipm.ac.cn/handle/112942/4444] |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, S,Wang, YM,Tang, BF,et al. Ultraviolet photodissociation of 1-bromopropane at 234 and 267 nm[J]. CHEMICAL PHYSICS LETTERS,2005,413(1-3):129-134. |
APA | Zhang, S,Wang, YM,Tang, BF,Zheng, QS,&Zhang, B.(2005).Ultraviolet photodissociation of 1-bromopropane at 234 and 267 nm.CHEMICAL PHYSICS LETTERS,413(1-3),129-134. |
MLA | Zhang, S,et al."Ultraviolet photodissociation of 1-bromopropane at 234 and 267 nm".CHEMICAL PHYSICS LETTERS 413.1-3(2005):129-134. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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