Biomemic synthesis, crystal structure of molybdenum and tungsten chiral octahedral Complex(NH3CH2CH2CH2NH2)(2) [Mo0.4W0.6O2(C6H4O2)(2)] and its interaction with ATP by H-1, C-13, P-31 and, (NMR)-N-15
文献类型：期刊论文
| 作者 | Lu, XM; Deng, Y; Li, L; Jiang, L; Mao, XA; Ye, CH |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2005-04-10 |
| 卷号 | 26期号:4页码:611-616 |
| 关键词 | molybdenum and tungsten chiral oitahedral complex crystal structure NMR ATP |
| 英文摘要 | A chiral octahedral molybdenum complex (NH3CH2CH2CH2NH2)(2)[Mo0.4W0.6O2 (C6H4O2)(2)] was obtained by the reaction of tetra-butyl. ammonium beta-octamolybdate with catechole and 1, 3-diaminopropane in the mixed solvent of CH3OH and CH3CN, characterized by X-ray diffraction, and its interaction with ATP was studied by H-1, C-13, P-31 and N-15 NMR. The crystal is orthorhombic with space group Pcan, a = 0.750 1(.2) nm, b = 2.399 4(7) nm, c = 1. 217 80) nm, Z = 4. The central metal ion exhibits distorted octahedral coordination with cis dioxo catechole. The H-1 and C-13 NMR studies reveal that the central metals were reduced to M ( V) and a little catecholato ligand was hydrolyzed when the complex is dissolved in D2O but were oxidized to M( W) and almost part of catecholato ligands dissociated with the central metals while it is mixed with ATP in D2O The shift of the H-1, C-13, P-31 and N-15 chemical shifts in adenine of ATP suggest that there is a coordinated interaction between central metal and the N atoms in adenine, and the coordination might be responsible for the anti-tumor and DNA cleavage activities of the title complex. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | EPR ; COMPLEXES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000228675700005 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4550]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, XM,Deng, Y,Li, L,et al. Biomemic synthesis, crystal structure of molybdenum and tungsten chiral octahedral Complex(NH3CH2CH2CH2NH2)(2) [Mo0.4W0.6O2(C6H4O2)(2)] and its interaction with ATP by H-1, C-13, P-31 and, (NMR)-N-15[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2005,26(4):611-616. |
| APA | Lu, XM,Deng, Y,Li, L,Jiang, L,Mao, XA,&Ye, CH.(2005).Biomemic synthesis, crystal structure of molybdenum and tungsten chiral octahedral Complex(NH3CH2CH2CH2NH2)(2) [Mo0.4W0.6O2(C6H4O2)(2)] and its interaction with ATP by H-1, C-13, P-31 and, (NMR)-N-15.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,26(4),611-616. |
| MLA | Lu, XM,et al."Biomemic synthesis, crystal structure of molybdenum and tungsten chiral octahedral Complex(NH3CH2CH2CH2NH2)(2) [Mo0.4W0.6O2(C6H4O2)(2)] and its interaction with ATP by H-1, C-13, P-31 and, (NMR)-N-15".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 26.4(2005):611-616. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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