Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study
文献类型:期刊论文
作者 | Wang, JQ; Yu, NY; Zheng, AM; Yang, J; Wu, D; Sun, YH; Ye, CH; Deng, F |
刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
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出版日期 | 2006-02-24 |
卷号 | 89期号:1-3页码:219-226 |
关键词 | bronsted acidity DFT calculation solid-state NMR spectroscopy sulfonic-functionalized MSU mesoporous material |
英文摘要 | The structure and acidity of sulfonic group functionalized mesoporous materials with MSU structure were characterized in detail using multinuclear NMR technique in combination with other approaches such as XRD, N-2 adsorption and desorption, as well as density function theory (DFT) calculation. Our experimental and theoretical calculation results indicate that functionalized MSU-SO3H materials with well-ordered mesostructure have been successfully synthesized and the materials have acid strength slightly weaker than that of microporous zeolite HZSM-5, which may be helpful for the understanding of some acid-catalyzed reactions, such as alkylation and esterification, occurring on sulfonic-functionalized mesoporous materials. (c) 2005 Elsevier Inc. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
关键词[WOS] | SOLID-STATE NMR ; IN-SITU NMR ; MOLECULAR-SIEVES ; ALUMINUM-CHLORIDE ; PROBE MOLECULE ; ACID SITES ; SILICA ; ZEOLITES ; TRIMETHYLPHOSPHINE ; CHEMISTRY |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000235441600028 |
公开日期 | 2015-07-28 |
源URL | [http://ir.wipm.ac.cn/handle/112942/4623] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, JQ,Yu, NY,Zheng, AM,et al. Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2006,89(1-3):219-226. |
APA | Wang, JQ.,Yu, NY.,Zheng, AM.,Yang, J.,Wu, D.,...&Deng, F.(2006).Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study.MICROPOROUS AND MESOPOROUS MATERIALS,89(1-3),219-226. |
MLA | Wang, JQ,et al."Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study".MICROPOROUS AND MESOPOROUS MATERIALS 89.1-3(2006):219-226. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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