中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study

文献类型:期刊论文

作者Wang, JQ; Yu, NY; Zheng, AM; Yang, J; Wu, D; Sun, YH; Ye, CH; Deng, F
刊名MICROPOROUS AND MESOPOROUS MATERIALS
出版日期2006-02-24
卷号89期号:1-3页码:219-226
关键词bronsted acidity DFT calculation solid-state NMR spectroscopy sulfonic-functionalized MSU mesoporous material
英文摘要The structure and acidity of sulfonic group functionalized mesoporous materials with MSU structure were characterized in detail using multinuclear NMR technique in combination with other approaches such as XRD, N-2 adsorption and desorption, as well as density function theory (DFT) calculation. Our experimental and theoretical calculation results indicate that functionalized MSU-SO3H materials with well-ordered mesostructure have been successfully synthesized and the materials have acid strength slightly weaker than that of microporous zeolite HZSM-5, which may be helpful for the understanding of some acid-catalyzed reactions, such as alkylation and esterification, occurring on sulfonic-functionalized mesoporous materials. (c) 2005 Elsevier Inc. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science
关键词[WOS]SOLID-STATE NMR ; IN-SITU NMR ; MOLECULAR-SIEVES ; ALUMINUM-CHLORIDE ; PROBE MOLECULE ; ACID SITES ; SILICA ; ZEOLITES ; TRIMETHYLPHOSPHINE ; CHEMISTRY
收录类别SCI
语种英语
WOS记录号WOS:000235441600028
公开日期2015-07-28
源URL[http://ir.wipm.ac.cn/handle/112942/4623]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
2.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
推荐引用方式
GB/T 7714
Wang, JQ,Yu, NY,Zheng, AM,et al. Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2006,89(1-3):219-226.
APA Wang, JQ.,Yu, NY.,Zheng, AM.,Yang, J.,Wu, D.,...&Deng, F.(2006).Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study.MICROPOROUS AND MESOPOROUS MATERIALS,89(1-3),219-226.
MLA Wang, JQ,et al."Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study".MICROPOROUS AND MESOPOROUS MATERIALS 89.1-3(2006):219-226.

入库方式: OAI收割

来源:武汉物理与数学研究所

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