Mass analyzed threshold ionization spectra of ethyl bromide
文献类型:期刊论文
作者 | Tang Bi-Feng; Xiong Ping-Fan; Zhang Xiu; Zhang Bing |
刊名 | ACTA PHYSICA SINICA
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出版日期 | 2006-09-01 |
卷号 | 55期号:9页码:4483-4489 |
关键词 | mass analyzed threshold ionization (MATI) spectrum vibrational mode one-color two-photon zero kinetic energy (ZEKE) photoelectron spectroscopy ethyl bromide |
英文摘要 | Using one-color two-photon (1C2P) scheme, high-resolution mass analyzed threshold ionization MATI spectra of ethyl bromide have been recorded. Accurate values for the adiabatic ionization energy have been determined to be 83097 +/- 3 cm(-1) and 85452 +/- 3 cm(-1) for the (X1E1/2)-E-2 and (X2E1/2)-E-2 states of the cation, respectively, giving a splitting of 2355 +/- 6 cm(-1). The ionic vibrational frequencies were also obtained, and the values were in agreement with high accuracy with the literature data. The spectra showed extensive excited vibrational structure as a result of wave packet evolving on the potential energy surface of the dissociative state in the time interval between the absorption of the two photons. The vibrational calibration was done based on the known vibrational frequencies of the neutral ethyl bromide. The spectrum was found to exhibit mainly vibrational modes involving the dissociation of the molecule, including some non-totally symmetric modes. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Physics, Multidisciplinary |
研究领域[WOS] | Physics |
关键词[WOS] | ENERGY PHOTOELECTRON-SPECTROSCOPY ; 2-PHOTON IONIZATION ; RYDBERG STATES ; RESOLUTION ; CATION ; CH3I ; PHOTODISSOCIATION ; EXCITATION ; COMPLEXES ; ISOPROPYL |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000240390900015 |
公开日期 | 2015-07-28 |
源URL | [http://ir.wipm.ac.cn/handle/112942/4630] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Xiaogan Univ, Dept Phys, Xiaogan 432100, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
推荐引用方式 GB/T 7714 | Tang Bi-Feng,Xiong Ping-Fan,Zhang Xiu,et al. Mass analyzed threshold ionization spectra of ethyl bromide[J]. ACTA PHYSICA SINICA,2006,55(9):4483-4489. |
APA | Tang Bi-Feng,Xiong Ping-Fan,Zhang Xiu,&Zhang Bing.(2006).Mass analyzed threshold ionization spectra of ethyl bromide.ACTA PHYSICA SINICA,55(9),4483-4489. |
MLA | Tang Bi-Feng,et al."Mass analyzed threshold ionization spectra of ethyl bromide".ACTA PHYSICA SINICA 55.9(2006):4483-4489. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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