Structure and NMR spectroscopy in solid state and solution of {Na-2[mu(2)-(C6H4O2)(2)](C6H4OOH)(2)}(4-)
文献类型：期刊论文
| 作者 | Lu, XM; Li, L; Song, FG; Wang, B; Yuan, HZ; Ye, CH |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 24期号:3页码:336-340 |
| 关键词 | sodium complex 1 synthesis crystal structure 2-dihydroxybenzene |
| 英文摘要 | The new compound (NH3CH2CH2NH3)(2){Na-2[mu(2)-(C6H4O2)(2)](C6H4OOH)(2)} has been synthesized and characterized by elemental analysis, IR, LTV, NMR and single crystal X-ray diffraction. The yellow crystals crystallized in the triclinic system with space group P-1 and a=0.6091(2) nm, b=1.0274(3) nm, c=1.2466(4) mn, alpha=89.073(6)degrees, beta=89.376(6)degrees, gamma=78.873(5)degrees, V=0.7653(4) nm(3), Z=1, R-1=0.0568, wR(2)=0.1198. Every sodium ion coordinates in trigonal prismatic fashion with two 0 atoms from a terminal chelating catecholato ligand and four 0 atoms from bridging mu(2) catecholato ligands. Two neighboring NaO6 trigonal prisms are face-shared and centrosymmetric with regard to the inversion center consisting of four tri-bridging 0 atoms to form a binuclear cluster {Na-2[mu(2)-(C6H4O2)(2)]}(2-) anion. The comparison of C-13 NMR spectrum of the complex in solid state with that in solution indicated that the rapid exchange between the bridging [mu(2)-(C6H4O2)](2-) and terminal [C6H4OOH](-) ligands was present in solution. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TRANSITION-METAL COMPLEXES ; CRYSTAL-STRUCTURE ; EPR-SPECTRA ; CIS-DIOXO-MOLYBDENUM(V) ; SEMIQUINONE ; CATECHOL ; LIGANDS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000235990900009 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4642]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, XM,Li, L,Song, FG,et al. Structure and NMR spectroscopy in solid state and solution of {Na-2[mu(2)-(C6H4O2)(2)](C6H4OOH)(2)}(4-)[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(3):336-340. |
| APA | Lu, XM,Li, L,Song, FG,Wang, B,Yuan, HZ,&Ye, CH.(2006).Structure and NMR spectroscopy in solid state and solution of {Na-2[mu(2)-(C6H4O2)(2)](C6H4OOH)(2)}(4-).CHINESE JOURNAL OF CHEMISTRY,24(3),336-340. |
| MLA | Lu, XM,et al."Structure and NMR spectroscopy in solid state and solution of {Na-2[mu(2)-(C6H4O2)(2)](C6H4OOH)(2)}(4-)".CHINESE JOURNAL OF CHEMISTRY 24.3(2006):336-340. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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