中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The 1-bromoheptane photodissociation near 234 nm

文献类型:期刊论文

作者Qu Hongbo; Li Haiyang; Feng, Liang; Bing, Zhang
刊名CHEMICAL PHYSICS
出版日期2006-11-21
卷号330期号:3页码:355-359
关键词ion imaging adiabatic and non-adiabatic transition 1-bromoheptane
英文摘要The photodissociation of n-C7H15Br, near the red wing of the absorption A-band, has been investigated utilizing the velocity mapped ion imaging technique. Both the speed and angular distributions of Br-* ((2)p(1/2)) and Br(P-2(3/2)) fragments were determined. The experimental data indicate that the photodissociation in the investigated range originates from adiabatic and non-adiabatic transitions of the three low-lying dissociative electronic states. The fragments kinetic energies and the angular distributions show that about 70% energy is deposited into the internal energy of the fragments. These results can be explained using soft impulsive model. The experiment also shows that the anisotropy parameter for Br* is sensitive to the photolysis wavelength. (c) 2006 Elsevier B.V. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]ETHYL-BROMIDE ; DYNAMICS ; CH2BRCL ; CH3BR
收录类别SCI
语种英语
WOS记录号WOS:000242644600003
公开日期2015-07-28
源URL[http://ir.wipm.ac.cn/handle/112942/4791]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
3.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Qu Hongbo,Li Haiyang,Feng, Liang,et al. The 1-bromoheptane photodissociation near 234 nm[J]. CHEMICAL PHYSICS,2006,330(3):355-359.
APA Qu Hongbo,Li Haiyang,Feng, Liang,&Bing, Zhang.(2006).The 1-bromoheptane photodissociation near 234 nm.CHEMICAL PHYSICS,330(3),355-359.
MLA Qu Hongbo,et al."The 1-bromoheptane photodissociation near 234 nm".CHEMICAL PHYSICS 330.3(2006):355-359.

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来源:武汉物理与数学研究所

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