The 1-bromoheptane photodissociation near 234 nm
文献类型:期刊论文
作者 | Qu Hongbo; Li Haiyang; Feng, Liang; Bing, Zhang |
刊名 | CHEMICAL PHYSICS
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出版日期 | 2006-11-21 |
卷号 | 330期号:3页码:355-359 |
关键词 | ion imaging adiabatic and non-adiabatic transition 1-bromoheptane |
英文摘要 | The photodissociation of n-C7H15Br, near the red wing of the absorption A-band, has been investigated utilizing the velocity mapped ion imaging technique. Both the speed and angular distributions of Br-* ((2)p(1/2)) and Br(P-2(3/2)) fragments were determined. The experimental data indicate that the photodissociation in the investigated range originates from adiabatic and non-adiabatic transitions of the three low-lying dissociative electronic states. The fragments kinetic energies and the angular distributions show that about 70% energy is deposited into the internal energy of the fragments. These results can be explained using soft impulsive model. The experiment also shows that the anisotropy parameter for Br* is sensitive to the photolysis wavelength. (c) 2006 Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
研究领域[WOS] | Chemistry ; Physics |
关键词[WOS] | ETHYL-BROMIDE ; DYNAMICS ; CH2BRCL ; CH3BR |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000242644600003 |
公开日期 | 2015-07-28 |
源URL | [http://ir.wipm.ac.cn/handle/112942/4791] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China 3.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Qu Hongbo,Li Haiyang,Feng, Liang,et al. The 1-bromoheptane photodissociation near 234 nm[J]. CHEMICAL PHYSICS,2006,330(3):355-359. |
APA | Qu Hongbo,Li Haiyang,Feng, Liang,&Bing, Zhang.(2006).The 1-bromoheptane photodissociation near 234 nm.CHEMICAL PHYSICS,330(3),355-359. |
MLA | Qu Hongbo,et al."The 1-bromoheptane photodissociation near 234 nm".CHEMICAL PHYSICS 330.3(2006):355-359. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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