Influence of Al3+ on polymorph A enrichment in the crystallization of beta zeolite
文献类型:期刊论文
作者 | Lu, Tingting1; Gao, Pan2; Xu, Jun2; Wang, Yongrui3; Yan, Wenfu1; Yu, Jihong1; Deng, Feng2; Mu, Xuhong3; Xu, Ruren1 |
刊名 | CHINESE JOURNAL OF CATALYSIS
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出版日期 | 2015-06-01 |
卷号 | 36期号:6页码:889-896 |
关键词 | Beta zeolite Chirality Polymorph A Enrichment |
英文摘要 | Using tetraethylammonium hydroxide as the organic structure-directing agent and in the presence of fluoride, polymorph A-enriched silica beta zeolite was synthesized under concentrated hydrothermal conditions. The introduction of Al species into the same starting mixture resulted in a decrease in the degree of enrichment of polymorph A in beta zeolite and an Al-incorporated beta zeolite resulted. The crystallized polymorph A-enriched silica beta zeolite and the Al-incorporated beta zeolite and their crystallization processes were investigated by X-ray diffractometry, elemental analysis, thermogravimetric analysis-differential thermal analysis, nitrogen adsorption, scanning electron microscopy, and solid-state magic angle spinning nuclear magnetic resonance. The introduction of Al species accelerated crystallization and reduced the crystal size of Al-incorporated beta zeolite. The intermediate of five-coordinated Al species accounted for a decrease in the degree of enrichment of polymorph A in the crystallization of Al-incorporated beta zeolite. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
研究领域[WOS] | Chemistry ; Engineering |
关键词[WOS] | FLUORIDE MEDIUM ; MECHANISM ; CATALYST ; MEDIA |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000355499500015 |
公开日期 | 2015-07-28 |
源URL | [http://ir.wipm.ac.cn/handle/112942/4753] ![]() |
专题 | 武汉物理与数学研究所_磁共振应用研究部 |
作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 3.SINOPEC, Res Inst Petr Proc, State Key Lab Catalyt Mat & React Engn, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Lu, Tingting,Gao, Pan,Xu, Jun,et al. Influence of Al3+ on polymorph A enrichment in the crystallization of beta zeolite[J]. CHINESE JOURNAL OF CATALYSIS,2015,36(6):889-896. |
APA | Lu, Tingting.,Gao, Pan.,Xu, Jun.,Wang, Yongrui.,Yan, Wenfu.,...&Xu, Ruren.(2015).Influence of Al3+ on polymorph A enrichment in the crystallization of beta zeolite.CHINESE JOURNAL OF CATALYSIS,36(6),889-896. |
MLA | Lu, Tingting,et al."Influence of Al3+ on polymorph A enrichment in the crystallization of beta zeolite".CHINESE JOURNAL OF CATALYSIS 36.6(2015):889-896. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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