Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route
文献类型：期刊论文
| 作者 | Tong, Mingquan1; Zhang, Daliang1; Fan, Weibin2; Xu, Jun3; Zhu, Liangkui1; Guo, Wen1; Yan, Wenfu1; Yu, Jihong1; Qiu, Shilun1; Wang, Jianguo2 |
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2015-06-22 |
| 卷号 | 5 |
| 英文摘要 | Chiral zeolitic materials with intrinsically chiral frameworks are highly desired because they can combine both shape selectivity and enantioselectivity. In the field of zeolite, the synthesis of chiral polymorph A of zeolite Beta or chiral polymorph A-enriched zeolite Beta is one of the biggest challenges. We demonstrate here a generalized extremely concentrated fluoride route for the synthesis of chiral polymorph A-enriched zeolite Beta in the presence of five achiral organic structure-directing agents. The polymorph A-enriched Ti-Beta shows a higher enantioselectivity for the asymmetric epoxidation of alkenes than the normal Ti-Beta. |
| WOS标题词 | Science & Technology |
| 类目[WOS] | Multidisciplinary Sciences |
| 研究领域[WOS] | Science & Technology - Other Topics |
| 关键词[WOS] | CRYSTAL-STRUCTURE ; FRAMEWORK ; TOPOLOGY ; CHANNELS ; DEFECTS ; GROWTH |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356597100001 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4762]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Jilin Univ, Dept Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Mingquan,Zhang, Daliang,Fan, Weibin,et al. Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route[J]. SCIENTIFIC REPORTS,2015,5. |
| APA | Tong, Mingquan.,Zhang, Daliang.,Fan, Weibin.,Xu, Jun.,Zhu, Liangkui.,...&Xu, Ruren.(2015).Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route.SCIENTIFIC REPORTS,5. |
| MLA | Tong, Mingquan,et al."Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route".SCIENTIFIC REPORTS 5(2015). |
入库方式： OAI收割
来源：武汉物理与数学研究所
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